A new synthetic strategy for magnetic metal bis(dithiolene) based conductors

MJJ Mulder; DJ Stufkens; LH Tjeng; HJ Lin; CT Chen; J Reedijk

A new synthetic strategy for magnetic metal bis(dithiolene) based conductors

MJJ Mulder
, DJ Stufkens
, LH Tjeng
, HJ Lin
, CT Chen
, J Reedijk^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

4 Citations (Scopus)

Abstract

The combination of the [Co-III(Cl-2-bpy)(3)](3+) complex with the [Ni(dmit)(2)](-) anion is a one-step reaction, which results in the partially oxidised Ni(dmit)(2)-based material [Co-II(C;(2)-bpy)(3)][Ni(dmit)(2)](5) with a paramagnetic Con cation, as proven by Raman, EPR and XAS, exemplifying a, for M(dithiolene)(2) compounds new, synthetic strategy that may give access to a large variety of new [Co-II(N,N-imine)(3)][M(dithiolene)(2)] (n > 2, M = Ni, Pd) type magnetic conductors.

Original language	English
Pages (from-to)	3083-3086
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	12
Publication status	Published - Dec-2002

Keywords

redox chemistry
conducting materials
X-ray absorption spectroscopy
EPR spectroscopy
Raman spectroscopy
CHARGE-TRANSFER COMPLEXES
M(DMIT)(2) SALTS
1,10-PHENANTHROLINE
PD

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title = "A new synthetic strategy for magnetic metal bis(dithiolene) based conductors",

abstract = "The combination of the [Co-III(Cl-2-bpy)(3)](3+) complex with the [Ni(dmit)(2)](-) anion is a one-step reaction, which results in the partially oxidised Ni(dmit)(2)-based material [Co-II(C;(2)-bpy)(3)][Ni(dmit)(2)](5) with a paramagnetic Con cation, as proven by Raman, EPR and XAS, exemplifying a, for M(dithiolene)(2) compounds new, synthetic strategy that may give access to a large variety of new [Co-II(N,N-imine)(3)][M(dithiolene)(2)] (n > 2, M = Ni, Pd) type magnetic conductors.",

keywords = "redox chemistry, conducting materials, X-ray absorption spectroscopy, EPR spectroscopy, Raman spectroscopy, CHARGE-TRANSFER COMPLEXES, M(DMIT)(2) SALTS, 1,10-PHENANTHROLINE, PD",

author = "MJJ Mulder and DJ Stufkens and LH Tjeng and HJ Lin and CT Chen and J Reedijk",

year = "2002",

month = dec,

language = "English",

pages = "3083--3086",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "WILEY-V C H VERLAG GMBH",

number = "12",

}

TY - JOUR

T1 - A new synthetic strategy for magnetic metal bis(dithiolene) based conductors

AU - Mulder, MJJ

AU - Stufkens, DJ

AU - Tjeng, LH

AU - Lin, HJ

AU - Chen, CT

AU - Reedijk, J

PY - 2002/12

Y1 - 2002/12

N2 - The combination of the [Co-III(Cl-2-bpy)(3)](3+) complex with the [Ni(dmit)(2)](-) anion is a one-step reaction, which results in the partially oxidised Ni(dmit)(2)-based material [Co-II(C;(2)-bpy)(3)][Ni(dmit)(2)](5) with a paramagnetic Con cation, as proven by Raman, EPR and XAS, exemplifying a, for M(dithiolene)(2) compounds new, synthetic strategy that may give access to a large variety of new [Co-II(N,N-imine)(3)][M(dithiolene)(2)] (n > 2, M = Ni, Pd) type magnetic conductors.

AB - The combination of the [Co-III(Cl-2-bpy)(3)](3+) complex with the [Ni(dmit)(2)](-) anion is a one-step reaction, which results in the partially oxidised Ni(dmit)(2)-based material [Co-II(C;(2)-bpy)(3)][Ni(dmit)(2)](5) with a paramagnetic Con cation, as proven by Raman, EPR and XAS, exemplifying a, for M(dithiolene)(2) compounds new, synthetic strategy that may give access to a large variety of new [Co-II(N,N-imine)(3)][M(dithiolene)(2)] (n > 2, M = Ni, Pd) type magnetic conductors.

KW - redox chemistry

KW - conducting materials

KW - X-ray absorption spectroscopy

KW - EPR spectroscopy

KW - Raman spectroscopy

KW - CHARGE-TRANSFER COMPLEXES

KW - M(DMIT)(2) SALTS

KW - 1,10-PHENANTHROLINE

KW - PD

M3 - Article

SN - 1434-1948

SP - 3083

EP - 3086

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 12

ER -

A new synthetic strategy for magnetic metal bis(dithiolene) based conductors

Abstract

Keywords

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