Abstract
The hydrothermal reaction of Co(NO3)(2)center dot 6H(2)O and a new designed ligand H2DCNT yields a three-dimensional polymer [Co(DCNT) (H2O)(n) (1), H2DCNT=2,4-bis(4-carboxyphenylamino)-6-diethylamino-1,3,5-triazine. In the structure of 1, each DCNT2- has three coordination sites, one nitrogen atom in the triazine ring coordinating to Co(II) and two carboxylates adopting mu(2)-bridging mode, which make the infinite Co(II) chains array uniformly and evenly toward crystallographic c-axis. Luminescent and magnetic properties of 1 were also studied. (c) 2007 Elsevier B.V. All rights reserved.
Original language | English |
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Pages (from-to) | 910-913 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 10 |
Issue number | 8 |
DOIs | |
Publication status | Published - Aug-2007 |
Keywords
- hydrothermal method
- coordination polymer
- luminescence
- magnetic property
- METAL-ORGANIC FRAMEWORKS
- CRYSTAL-STRUCTURES
- COORDINATION POLYMERS
- BUILDING-BLOCKS
- CHAIN COMPOUND
- DESIGN
- NETWORKS
- SOLIDS
- CO
- FORMATE
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CCDC 621232: Experimental Crystal Structure Determination
Wei, Y. (Contributor), Wu, K. (Contributor), Braam, R. (Contributor), Zhuang, B. (Contributor) & Yu, Y. (Contributor), University of Groningen, 17-Sept-2006
DOI: 10.5517/ccnvfrn
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