A polymeric cobalt compound [Co(DCNT)(H2O)](n) with novel topology: Synthesis, structure, luminescence, and magnetic property

Yongqin Wei; Kechen Wu; Ria Broer; Botao Zhuang; Yunfang Yu

doi:10.1016/j.inoche.2007.04.023

A polymeric cobalt compound [Co(DCNT)(H2O)](n) with novel topology: Synthesis, structure, luminescence, and magnetic property

Yongqin Wei, Kechen Wu^*, Ria Broer, Botao Zhuang, Yunfang Yu

^*Corresponding author for this work

Theoretical Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The hydrothermal reaction of Co(NO3)(2)center dot 6H(2)O and a new designed ligand H2DCNT yields a three-dimensional polymer [Co(DCNT) (H2O)(n) (1), H2DCNT=2,4-bis(4-carboxyphenylamino)-6-diethylamino-1,3,5-triazine. In the structure of 1, each DCNT2- has three coordination sites, one nitrogen atom in the triazine ring coordinating to Co(II) and two carboxylates adopting mu(2)-bridging mode, which make the infinite Co(II) chains array uniformly and evenly toward crystallographic c-axis. Luminescent and magnetic properties of 1 were also studied. (c) 2007 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	910-913
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	8
DOIs	https://doi.org/10.1016/j.inoche.2007.04.023
Publication status	Published - Aug-2007

Keywords

hydrothermal method
coordination polymer
luminescence
magnetic property
METAL-ORGANIC FRAMEWORKS
CRYSTAL-STRUCTURES
COORDINATION POLYMERS
BUILDING-BLOCKS
CHAIN COMPOUND
DESIGN
NETWORKS
SOLIDS
CO
FORMATE

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CCDC 621232: Experimental Crystal Structure Determination
Wei, Y. (Contributor), Wu, K. (Contributor), Braam, R. (Contributor), Zhuang, B. (Contributor) & Yu, Y. (Contributor), University of Groningen, 17-Sept-2006
DOI: 10.5517/ccnvfrn
Dataset

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@article{e46c9c557b1e4439a327b924ff3b998a,

title = "A polymeric cobalt compound [Co(DCNT)(H2O)](n) with novel topology: Synthesis, structure, luminescence, and magnetic property",

abstract = "The hydrothermal reaction of Co(NO3)(2)center dot 6H(2)O and a new designed ligand H2DCNT yields a three-dimensional polymer [Co(DCNT) (H2O)(n) (1), H2DCNT=2,4-bis(4-carboxyphenylamino)-6-diethylamino-1,3,5-triazine. In the structure of 1, each DCNT2- has three coordination sites, one nitrogen atom in the triazine ring coordinating to Co(II) and two carboxylates adopting mu(2)-bridging mode, which make the infinite Co(II) chains array uniformly and evenly toward crystallographic c-axis. Luminescent and magnetic properties of 1 were also studied. (c) 2007 Elsevier B.V. All rights reserved.",

keywords = "hydrothermal method, coordination polymer, luminescence, magnetic property, METAL-ORGANIC FRAMEWORKS, CRYSTAL-STRUCTURES, COORDINATION POLYMERS, BUILDING-BLOCKS, CHAIN COMPOUND, DESIGN, NETWORKS, SOLIDS, CO, FORMATE",

author = "Yongqin Wei and Kechen Wu and Ria Broer and Botao Zhuang and Yunfang Yu",

year = "2007",

month = aug,

doi = "10.1016/j.inoche.2007.04.023",

language = "English",

volume = "10",

pages = "910--913",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "8",

}

TY - JOUR

T1 - A polymeric cobalt compound [Co(DCNT)(H2O)](n) with novel topology

T2 - Synthesis, structure, luminescence, and magnetic property

AU - Wei, Yongqin

AU - Wu, Kechen

AU - Broer, Ria

AU - Zhuang, Botao

AU - Yu, Yunfang

PY - 2007/8

Y1 - 2007/8

N2 - The hydrothermal reaction of Co(NO3)(2)center dot 6H(2)O and a new designed ligand H2DCNT yields a three-dimensional polymer [Co(DCNT) (H2O)(n) (1), H2DCNT=2,4-bis(4-carboxyphenylamino)-6-diethylamino-1,3,5-triazine. In the structure of 1, each DCNT2- has three coordination sites, one nitrogen atom in the triazine ring coordinating to Co(II) and two carboxylates adopting mu(2)-bridging mode, which make the infinite Co(II) chains array uniformly and evenly toward crystallographic c-axis. Luminescent and magnetic properties of 1 were also studied. (c) 2007 Elsevier B.V. All rights reserved.

AB - The hydrothermal reaction of Co(NO3)(2)center dot 6H(2)O and a new designed ligand H2DCNT yields a three-dimensional polymer [Co(DCNT) (H2O)(n) (1), H2DCNT=2,4-bis(4-carboxyphenylamino)-6-diethylamino-1,3,5-triazine. In the structure of 1, each DCNT2- has three coordination sites, one nitrogen atom in the triazine ring coordinating to Co(II) and two carboxylates adopting mu(2)-bridging mode, which make the infinite Co(II) chains array uniformly and evenly toward crystallographic c-axis. Luminescent and magnetic properties of 1 were also studied. (c) 2007 Elsevier B.V. All rights reserved.

KW - hydrothermal method

KW - coordination polymer

KW - luminescence

KW - magnetic property

KW - METAL-ORGANIC FRAMEWORKS

KW - CRYSTAL-STRUCTURES

KW - COORDINATION POLYMERS

KW - BUILDING-BLOCKS

KW - CHAIN COMPOUND

KW - DESIGN

KW - NETWORKS

KW - SOLIDS

KW - CO

KW - FORMATE

U2 - 10.1016/j.inoche.2007.04.023

DO - 10.1016/j.inoche.2007.04.023

M3 - Article

SN - 1387-7003

VL - 10

SP - 910

EP - 913

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 8

ER -

A polymeric cobalt compound [Co(DCNT)(H2O)](n) with novel topology: Synthesis, structure, luminescence, and magnetic property

Abstract

Keywords

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CCDC 621232: Experimental Crystal Structure Determination

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