An efficient method to prepare supported bismuth nanoparticles as highly selective electrocatalyst for the conversion of CO2 into formate

Matteo Miola; Bart C A de Jong; Paolo P Pescarmona

doi:10.1039/d0cc06818g

An efficient method to prepare supported bismuth nanoparticles as highly selective electrocatalyst for the conversion of CO2 into formate

Matteo Miola, Bart C A de Jong, Paolo P Pescarmona^*

^*Corresponding author for this work

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Abstract

We report a cost-effective, straightforward synthesis of a novel electrocatalyst for the reduction of CO2 to formate, which achieves nearly complete Faradaic efficiency (FE) at an overpotential (η) of 0.88 V under ambient conditions. The electrocatalyst was prepared using bismuth subsalicylate as precursor and consists of bismuth nanoparticles (Bi NPs) with an average diameter of 5.5 nm supported on activated carbon. This journal is

Original language	English
Pages (from-to)	14992-14995
Number of pages	4
Journal	Chemical communications (Cambridge, England)
Volume	56
Issue number	95
Early online date	16-Nov-2020
DOIs	https://doi.org/10.1039/d0cc06818g
Publication status	Published - 11-Dec-2020

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10.1039/d0cc06818gLicence: CC BY

An efficient method to prepare supported bismuth nanoparticles as highly selective electrocatalyst for the conversion of CO2 into formateFinal publisher's version, 2.67 MBLicence: CC BY

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An efficient method to prepare supported bismuth nanoparticles as highly selective electrocatalyst for the conversion of CO2 into formate. / Miola, Matteo; de Jong, Bart C A ; Pescarmona, Paolo P.
In: Chemical communications (Cambridge, England), Vol. 56, No. 95, 11.12.2020, p. 14992-14995.

Research output: Contribution to journal › Article › Academic › peer-review

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T1 - An efficient method to prepare supported bismuth nanoparticles as highly selective electrocatalyst for the conversion of CO2 into formate

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AU - de Jong, Bart C A

AU - Pescarmona, Paolo P

PY - 2020/12/11

Y1 - 2020/12/11

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AB - We report a cost-effective, straightforward synthesis of a novel electrocatalyst for the reduction of CO2 to formate, which achieves nearly complete Faradaic efficiency (FE) at an overpotential (η) of 0.88 V under ambient conditions. The electrocatalyst was prepared using bismuth subsalicylate as precursor and consists of bismuth nanoparticles (Bi NPs) with an average diameter of 5.5 nm supported on activated carbon. This journal is

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SN - 1359-7345

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JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

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An efficient method to prepare supported bismuth nanoparticles as highly selective electrocatalyst for the conversion of CO2 into formate

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