C60/metal surfaces: adsorption and decomposition

M. Pedio; K. Hevesi; N. Zema; M. Capozi; P. Perfetti; R. Gouttebaron; J.-J. Pireaux; R. Caudano; P. Rudolf

doi:10.1016/S0039-6028(99)00732-3

C60/metal surfaces: adsorption and decomposition

M. Pedio, K. Hevesi, N. Zema, M. Capozi, P. Perfetti, R. Gouttebaron, J.-J. Pireaux, R. Caudano, P. Rudolf

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Abstract

C60 was deposited on Ni(110), Pt(111) and Ag(111) and annealed at different temperatures. The structural properties of the overlayer were investigated by low-energy electron diffraction, the changes induced by adsorption on its electronic properties were studied by valence band and core-level photoemission spectroscopy and inverse photoemission spectroscopy. On all surfaces C60 is chemisorbed and a clear signature for charge transfer is found for C60 on Ni(110) and Ag(111). Decomposition of C60 takes place on Ni(110) and Pt(111) above 690 K and 560 K respectively. The decomposition is a kinetically limited reaction on both surfaces and on Pt(111) we find a very strongly chemisorbed precursor state for decomposition.

Original language	English
Pages (from-to)	249-260
Number of pages	12
Journal	Surface Science
Volume	437
Issue number	1-2
DOIs	https://doi.org/10.1016/S0039-6028(99)00732-3
Publication status	Published - 1999
Externally published	Yes

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title = "C60/metal surfaces: adsorption and decomposition",

abstract = "C60 was deposited on Ni(110), Pt(111) and Ag(111) and annealed at different temperatures. The structural properties of the overlayer were investigated by low-energy electron diffraction, the changes induced by adsorption on its electronic properties were studied by valence band and core-level photoemission spectroscopy and inverse photoemission spectroscopy. On all surfaces C60 is chemisorbed and a clear signature for charge transfer is found for C60 on Ni(110) and Ag(111). Decomposition of C60 takes place on Ni(110) and Pt(111) above 690 K and 560 K respectively. The decomposition is a kinetically limited reaction on both surfaces and on Pt(111) we find a very strongly chemisorbed precursor state for decomposition.",

author = "M. Pedio and K. Hevesi and N. Zema and M. Capozi and P. Perfetti and R. Gouttebaron and J.-J. Pireaux and R. Caudano and P. Rudolf",

note = "Relation: http://www.rug.nl/natuurkunde/ date_submitted:2006 Rights: University of Groningen. Materials Science Centre",

year = "1999",

doi = "10.1016/S0039-6028(99)00732-3",

language = "English",

volume = "437",

pages = "249--260",

journal = "Surface Science",

issn = "0039-6028",

publisher = "ELSEVIER SCIENCE BV",

number = "1-2",

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TY - JOUR

T1 - C60/metal surfaces

T2 - adsorption and decomposition

AU - Pedio, M.

AU - Hevesi, K.

AU - Zema, N.

AU - Capozi, M.

AU - Perfetti, P.

AU - Gouttebaron, R.

AU - Pireaux, J.-J.

AU - Caudano, R.

AU - Rudolf, P.

N1 - Relation: http://www.rug.nl/natuurkunde/ date_submitted:2006 Rights: University of Groningen. Materials Science Centre

PY - 1999

Y1 - 1999

N2 - C60 was deposited on Ni(110), Pt(111) and Ag(111) and annealed at different temperatures. The structural properties of the overlayer were investigated by low-energy electron diffraction, the changes induced by adsorption on its electronic properties were studied by valence band and core-level photoemission spectroscopy and inverse photoemission spectroscopy. On all surfaces C60 is chemisorbed and a clear signature for charge transfer is found for C60 on Ni(110) and Ag(111). Decomposition of C60 takes place on Ni(110) and Pt(111) above 690 K and 560 K respectively. The decomposition is a kinetically limited reaction on both surfaces and on Pt(111) we find a very strongly chemisorbed precursor state for decomposition.

AB - C60 was deposited on Ni(110), Pt(111) and Ag(111) and annealed at different temperatures. The structural properties of the overlayer were investigated by low-energy electron diffraction, the changes induced by adsorption on its electronic properties were studied by valence band and core-level photoemission spectroscopy and inverse photoemission spectroscopy. On all surfaces C60 is chemisorbed and a clear signature for charge transfer is found for C60 on Ni(110) and Ag(111). Decomposition of C60 takes place on Ni(110) and Pt(111) above 690 K and 560 K respectively. The decomposition is a kinetically limited reaction on both surfaces and on Pt(111) we find a very strongly chemisorbed precursor state for decomposition.

U2 - 10.1016/S0039-6028(99)00732-3

DO - 10.1016/S0039-6028(99)00732-3

M3 - Article

SN - 0039-6028

VL - 437

SP - 249

EP - 260

JO - Surface Science

JF - Surface Science

IS - 1-2

ER -

C60/metal surfaces: adsorption and decomposition

Abstract

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