C60/metal surfaces: adsorption and decomposition

M. Pedio; K. Hevesi; N. Zema; M. Capozi; P. Perfetti; R. Gouttebaron; J.-J. Pireaux; R. Caudano; P. Rudolf

doi:10.1016/S0039-6028(99)00732-3

C60/metal surfaces: adsorption and decomposition

M. Pedio
, K. Hevesi
, N. Zema
, M. Capozi
, P. Perfetti
, R. Gouttebaron
, J.-J. Pireaux
, R. Caudano
, P. Rudolf

Research output: Contribution to journal › Article › Academic › peer-review

69 Citations (Scopus)

209 Downloads (Pure)

Abstract

C60 was deposited on Ni(110), Pt(111) and Ag(111) and annealed at different temperatures. The structural properties of the overlayer were investigated by low-energy electron diffraction, the changes induced by adsorption on its electronic properties were studied by valence band and core-level photoemission spectroscopy and inverse photoemission spectroscopy. On all surfaces C60 is chemisorbed and a clear signature for charge transfer is found for C60 on Ni(110) and Ag(111). Decomposition of C60 takes place on Ni(110) and Pt(111) above 690 K and 560 K respectively. The decomposition is a kinetically limited reaction on both surfaces and on Pt(111) we find a very strongly chemisorbed precursor state for decomposition.

Original language	English
Pages (from-to)	249-260
Number of pages	12
Journal	Surface Science
Volume	437
Issue number	1-2
DOIs	https://doi.org/10.1016/S0039-6028(99)00732-3
Publication status	Published - 1999
Externally published	Yes

Access to Document

10.1016/S0039-6028(99)00732-3

Handle.net

Persistent link

Embargoed Document

C60/metal surfaces: adsorption and decomposition
Final publisher's version, 384 KB
Request copy

Cite this

@article{015434450669467b82d69a6c2891191d,

title = "C60/metal surfaces: adsorption and decomposition",

abstract = "C60 was deposited on Ni(110), Pt(111) and Ag(111) and annealed at different temperatures. The structural properties of the overlayer were investigated by low-energy electron diffraction, the changes induced by adsorption on its electronic properties were studied by valence band and core-level photoemission spectroscopy and inverse photoemission spectroscopy. On all surfaces C60 is chemisorbed and a clear signature for charge transfer is found for C60 on Ni(110) and Ag(111). Decomposition of C60 takes place on Ni(110) and Pt(111) above 690 K and 560 K respectively. The decomposition is a kinetically limited reaction on both surfaces and on Pt(111) we find a very strongly chemisorbed precursor state for decomposition.",

author = "M. Pedio and K. Hevesi and N. Zema and M. Capozi and P. Perfetti and R. Gouttebaron and J.-J. Pireaux and R. Caudano and P. Rudolf",

note = "Relation: http://www.rug.nl/natuurkunde/ date\_submitted:2006 Rights: University of Groningen. Materials Science Centre",

year = "1999",

doi = "10.1016/S0039-6028(99)00732-3",

language = "English",

volume = "437",

pages = "249--260",

journal = "Surface Science",

issn = "0039-6028",

publisher = "ELSEVIER SCIENCE BV",

number = "1-2",

}

TY - JOUR

T1 - C60/metal surfaces

T2 - adsorption and decomposition

AU - Pedio, M.

AU - Hevesi, K.

AU - Zema, N.

AU - Capozi, M.

AU - Perfetti, P.

AU - Gouttebaron, R.

AU - Pireaux, J.-J.

AU - Caudano, R.

AU - Rudolf, P.

N1 - Relation: http://www.rug.nl/natuurkunde/ date_submitted:2006 Rights: University of Groningen. Materials Science Centre

PY - 1999

Y1 - 1999

N2 - C60 was deposited on Ni(110), Pt(111) and Ag(111) and annealed at different temperatures. The structural properties of the overlayer were investigated by low-energy electron diffraction, the changes induced by adsorption on its electronic properties were studied by valence band and core-level photoemission spectroscopy and inverse photoemission spectroscopy. On all surfaces C60 is chemisorbed and a clear signature for charge transfer is found for C60 on Ni(110) and Ag(111). Decomposition of C60 takes place on Ni(110) and Pt(111) above 690 K and 560 K respectively. The decomposition is a kinetically limited reaction on both surfaces and on Pt(111) we find a very strongly chemisorbed precursor state for decomposition.

AB - C60 was deposited on Ni(110), Pt(111) and Ag(111) and annealed at different temperatures. The structural properties of the overlayer were investigated by low-energy electron diffraction, the changes induced by adsorption on its electronic properties were studied by valence band and core-level photoemission spectroscopy and inverse photoemission spectroscopy. On all surfaces C60 is chemisorbed and a clear signature for charge transfer is found for C60 on Ni(110) and Ag(111). Decomposition of C60 takes place on Ni(110) and Pt(111) above 690 K and 560 K respectively. The decomposition is a kinetically limited reaction on both surfaces and on Pt(111) we find a very strongly chemisorbed precursor state for decomposition.

U2 - 10.1016/S0039-6028(99)00732-3

DO - 10.1016/S0039-6028(99)00732-3

M3 - Article

SN - 0039-6028

VL - 437

SP - 249

EP - 260

JO - Surface Science

JF - Surface Science

IS - 1-2

ER -

C60/metal surfaces: adsorption and decomposition

Abstract

Access to Document

Handle.net

Embargoed Document

Fingerprint

Cite this