Catalytic enantioselective conjugate addition of dialkylzinc reagents to N-substituted-2,3-dehydro-4-piperidones

Radovan Šebesta, Maria Gabriella Pizzuti, Arnold J. Boersma, Adriaan J. Minnaard, Ben L. Feringa

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Abstract

The first, highly enantioselective, copper/phosphoramidite-catalyzed conjugate addition of dialkylzinc reagents to N-substituted 2,3-dehydro-4-piperidones is described.
Original languageEnglish
Pages (from-to)1711-1713
Number of pages3
JournalChemical Communications
Issue number13
DOIs
Publication statusPublished - 2005

Keywords

  • ORGANOZINC REAGENTS
  • ASYMMETRIC 1,4-ADDITION
  • NUCLEOPHILES
  • ALDEHYDES
  • LIGANDS
  • ROUTE

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