TY - JOUR
T1 - Cerium Aryloxides as Precursors for Monopentamethylcyclopentadienyl Organocerium(III) Compounds; X-Ray Crystal Structure of (η5-Pentamethylcyclopentadienyl)bis(2,6-di-t-butylphenoxo)cerium
AU - Heeres, Hero J.
AU - Meetsma, Auke
AU - Teuben, Jan H.
N1 - Relation: http://www.rug.nl/scheikunde/
date_submitted:2005
Rights: University of Groningen. Stratingh Institute
PY - 1988
Y1 - 1988
N2 - Tris(2,6-di-t-butylphenoxo)cerium reacts with (C5Me5)Li in pentane to form (η5-C5Me5)bis(2,6-di-t-butylphenoxo)cerium, whose structure was established by X-ray crystallography and which, on subsequent reaction with LiCH(SiMe3)2, gives a novel mono(C5Me5)cerium-bisalkyl complex, (C5Me5)Ce[CH(SiMe3)2]2.
AB - Tris(2,6-di-t-butylphenoxo)cerium reacts with (C5Me5)Li in pentane to form (η5-C5Me5)bis(2,6-di-t-butylphenoxo)cerium, whose structure was established by X-ray crystallography and which, on subsequent reaction with LiCH(SiMe3)2, gives a novel mono(C5Me5)cerium-bisalkyl complex, (C5Me5)Ce[CH(SiMe3)2]2.
U2 - 10.1039/c39880000962
DO - 10.1039/c39880000962
M3 - Article
VL - 8
JO - Journal of the Chemical Society%2C Chemical Communications
JF - Journal of the Chemical Society%2C Chemical Communications
IS - 14
ER -