Characterization of stationary/mobile phase combinations by using markers: Part 1. Preliminary results for the prediction of reversed-phase retention on various stationary phases

Age K. Smilde*, Chris H. P. Bruins, Pierre M. J. Coenegracht, Durk A. Doornbos

*Corresponding author for this work

    Research output: Contribution to journalArticleAcademicpeer-review

    8 Citations (Scopus)

    Abstract

    The characterization of stationary/mobile phase combinations can be done in a phenomenological way by measuring the k′ values of specific solutes, the markers. These markers can be chosen optimally from a set of test solutes with the use of multivariate techniques. When retention data of solutes on different stationary phases, with varying mobile-phase compositions, are available, a procedure is given to predict the retention of those solutes on new stationary phases. This procedure uses markers to characterize the new stationary/mobile phase combinations.
    Original languageEnglish
    Pages (from-to)95-104
    Number of pages10
    JournalAnalytica Chimica Acta
    Volume212
    Issue number1-2
    DOIs
    Publication statusPublished - 15-Sept-1988

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