CHARGE-EXCHANGE OF SWIFT MOLECULES H-2(+), H-2, CO2+ AND CO2, AT PD(111) SURFACES

T SCHLATHOLTER, W HEILAND, Thomas Schlathölter

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6 Citations (Scopus)

Abstract

Molecular ions and neutral molecules are scattered at 500 eV and at grazing incidence from metal surfaces. H-2(+) and CO2+ are subject to charge exchange processes which lead in part to dissociation. In the case of CO2 evidence for negative molecular ion formation is found. Potassium ''poisons'' the dissociation of H-2 on Pd. These findings are supported by comparison of different metals, Pd(111) and Pd(111) covered with a monolayer of K. The dissociation probability of H-2(+) and H-2(0) decreases at the K-covered surface, in the case of CO2+ and CO20 an increase is found. CO2+ on Pd(111) + K dissociates completely.

Original languageEnglish
Pages (from-to)352-355
Number of pages4
JournalNuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms
Volume100
Issue number2-3
Publication statusPublished - Jun-1995
Event10th International Workshop on Inelastic Ion-Surface Collisions (IISC-10) - GRAND TARGHEE RESORT, United Kingdom
Duration: 8-Aug-199412-Aug-1994

Keywords

  • PD(100) SURFACE
  • ADSORPTION
  • SCATTERING
  • AG(111)
  • HYDROGEN
  • PT(111)
  • OXYGEN
  • ALKALI
  • IONS
  • CHEMISORPTION

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