Complex chemistry with complex compounds

Robert Eichler; M. Asai; H. Brand; N. M. Chiera; A. Di Nitto; R. Dressler; Ch. E. Düllmann; J. Even; F. Fangli; M. Goetz; H. Haba; W. Hartmann; E. Jäger; D. Kaji; J. Kanaya; Y. Kaneya; J. Khuyagbaatar; B. Kindler; Y. Komori; B. Kraus; J. V. Kratz; J. Krier; Y. Kudou; N. Kurz; S. Miyashita; K. Morimoto; K. Morita; M. Murakami; Y. Nagame; K. Ooe; D. Piguet; N. Sato; T. K. Sato; J. Steiner; P. Steinegger; T. Sumita; M. Takeyama; K. Tanaka; T. Tomitsuka; A. Toyoshima; K. Tsukada; A. Türler; I. Usoltsev; Y. Wakabayashi; Y. Wang; N. Wiehl; Y. Wittwer; A. Yakushev; S. Yamaki; S. Yano; S. Yamaki; Z. Qin

doi:10.1051/epjconf/201613107005

Complex chemistry with complex compounds

Robert Eichler
, M. Asai
, H. Brand
, N. M. Chiera
, A. Di Nitto
, R. Dressler
, Ch. E. Düllmann
, J. Even
, F. Fangli
, M. Goetz
, H. Haba
, W. Hartmann
, E. Jäger
, D. Kaji
, J. Kanaya
, Y. Kaneya
, J. Khuyagbaatar
, B. Kindler
, Y. Komori
, B. Kraus

J. V. Kratz, J. Krier, Y. Kudou, N. Kurz, S. Miyashita, K. Morimoto, K. Morita, M. Murakami, Y. Nagame, K. Ooe, D. Piguet, N. Sato, T. K. Sato, J. Steiner, P. Steinegger, T. Sumita, M. Takeyama, K. Tanaka, T. Tomitsuka, A. Toyoshima, K. Tsukada, A. Türler, I. Usoltsev, Y. Wakabayashi, Y. Wang, N. Wiehl, Y. Wittwer, A. Yakushev, S. Yamaki, S. Yano, S. Yamaki, Z. Qin

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Abstract

In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)6 was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of relativistic effects in the heaviest compounds. Our contribution comprises some aspects of the ongoing challenging experiments as well as an outlook towards other interesting compounds related to volatile complex compounds in the gas phase.

Original language	English
Article number	7005
Number of pages	7
Journal	EPJ Web of Conferences
Volume	131
DOIs	https://doi.org/10.1051/epjconf/201613107005
Publication status	Published - 1-Dec-2016
Externally published	Yes
Event	Nobel Symposium NS 160 – Chemistry and Physics of Heavy and Superheavy Elements - Fjälkinge, Sweden Duration: 29-May-2016 → 3-Jun-2016

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Eichler, R., Asai, M., Brand, H., Chiera, N. M., Di Nitto, A., Dressler, R., Düllmann, C. E., Even, J., Fangli, F., Goetz, M., Haba, H., Hartmann, W., Jäger, E., Kaji, D., Kanaya, J., Kaneya, Y., Khuyagbaatar, J., Kindler, B., Komori, Y., ... Qin, Z. (2016). Complex chemistry with complex compounds. EPJ Web of Conferences, 131, Article 7005. https://doi.org/10.1051/epjconf/201613107005

@article{00f4e4a8be624028bcdd30b4d05d9065,

title = "Complex chemistry with complex compounds",

abstract = "In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)6 was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of relativistic effects in the heaviest compounds. Our contribution comprises some aspects of the ongoing challenging experiments as well as an outlook towards other interesting compounds related to volatile complex compounds in the gas phase.",

author = "Robert Eichler and M. Asai and H. Brand and Chiera, \{N. M.\} and \{Di Nitto\}, A. and R. Dressler and D{\"u}llmann, \{Ch. E.\} and J. Even and F. Fangli and M. Goetz and H. Haba and W. Hartmann and E. J{\"a}ger and D. Kaji and J. Kanaya and Y. Kaneya and J. Khuyagbaatar and B. Kindler and Y. Komori and B. Kraus and Kratz, \{J. V.\} and J. Krier and Y. Kudou and N. Kurz and S. Miyashita and K. Morimoto and K. Morita and M. Murakami and Y. Nagame and K. Ooe and D. Piguet and N. Sato and Sato, \{T. K.\} and J. Steiner and P. Steinegger and T. Sumita and M. Takeyama and K. Tanaka and T. Tomitsuka and A. Toyoshima and K. Tsukada and A. T{\"u}rler and I. Usoltsev and Y. Wakabayashi and Y. Wang and N. Wiehl and Y. Wittwer and A. Yakushev and S. Yamaki and S. Yano and S. Yamaki and Z. Qin",

year = "2016",

month = dec,

day = "1",

doi = "10.1051/epjconf/201613107005",

language = "English",

volume = "131",

journal = "EPJ Web of Conferences",

issn = "2100-014X",

publisher = " EDP Sciences",

note = "Nobel Symposium NS 160 – Chemistry and Physics of Heavy and Superheavy Elements ; Conference date: 29-05-2016 Through 03-06-2016",

}

Eichler, R, Asai, M, Brand, H, Chiera, NM, Di Nitto, A, Dressler, R, Düllmann, CE, Even, J, Fangli, F, Goetz, M, Haba, H, Hartmann, W, Jäger, E, Kaji, D, Kanaya, J, Kaneya, Y, Khuyagbaatar, J, Kindler, B, Komori, Y, Kraus, B, Kratz, JV, Krier, J, Kudou, Y, Kurz, N, Miyashita, S, Morimoto, K, Morita, K, Murakami, M, Nagame, Y, Ooe, K, Piguet, D, Sato, N, Sato, TK, Steiner, J, Steinegger, P, Sumita, T, Takeyama, M, Tanaka, K, Tomitsuka, T, Toyoshima, A, Tsukada, K, Türler, A, Usoltsev, I, Wakabayashi, Y, Wang, Y, Wiehl, N, Wittwer, Y, Yakushev, A, Yamaki, S, Yano, S, Yamaki, S & Qin, Z 2016, 'Complex chemistry with complex compounds', EPJ Web of Conferences, vol. 131, 7005. https://doi.org/10.1051/epjconf/201613107005

TY - JOUR

T1 - Complex chemistry with complex compounds

AU - Eichler, Robert

AU - Asai, M.

AU - Brand, H.

AU - Chiera, N. M.

AU - Di Nitto, A.

AU - Dressler, R.

AU - Düllmann, Ch. E.

AU - Even, J.

AU - Fangli, F.

AU - Goetz, M.

AU - Haba, H.

AU - Hartmann, W.

AU - Jäger, E.

AU - Kaji, D.

AU - Kanaya, J.

AU - Kaneya, Y.

AU - Khuyagbaatar, J.

AU - Kindler, B.

AU - Komori, Y.

AU - Kraus, B.

AU - Kratz, J. V.

AU - Krier, J.

AU - Kudou, Y.

AU - Kurz, N.

AU - Miyashita, S.

AU - Morimoto, K.

AU - Morita, K.

AU - Murakami, M.

AU - Nagame, Y.

AU - Ooe, K.

AU - Piguet, D.

AU - Sato, N.

AU - Sato, T. K.

AU - Steiner, J.

AU - Steinegger, P.

AU - Sumita, T.

AU - Takeyama, M.

AU - Tanaka, K.

AU - Tomitsuka, T.

AU - Toyoshima, A.

AU - Tsukada, K.

AU - Türler, A.

AU - Usoltsev, I.

AU - Wakabayashi, Y.

AU - Wang, Y.

AU - Wiehl, N.

AU - Wittwer, Y.

AU - Yakushev, A.

AU - Yamaki, S.

AU - Yano, S.

AU - Yamaki, S.

AU - Qin, Z.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)6 was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of relativistic effects in the heaviest compounds. Our contribution comprises some aspects of the ongoing challenging experiments as well as an outlook towards other interesting compounds related to volatile complex compounds in the gas phase.

AB - In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)6 was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of relativistic effects in the heaviest compounds. Our contribution comprises some aspects of the ongoing challenging experiments as well as an outlook towards other interesting compounds related to volatile complex compounds in the gas phase.

U2 - 10.1051/epjconf/201613107005

DO - 10.1051/epjconf/201613107005

M3 - Article

SN - 2100-014X

VL - 131

JO - EPJ Web of Conferences

JF - EPJ Web of Conferences

M1 - 7005

T2 - Nobel Symposium NS 160 – Chemistry and Physics of Heavy and Superheavy Elements

Y2 - 29 May 2016 through 3 June 2016

ER -

Complex chemistry with complex compounds

Abstract

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