Composition and morphology control in ordered mesostructured high-temperature ceramics from block copolymer mesophases

Marleen Kamperman; Phong Du; Raluca O. Scarlat; Erik Herz; Ulrike Werner-Zwanziger; Robert Graf; Josef W. Zwanziger; Hans W. Spiess; Ulrich Wiesner

doi:10.1002/macp.200700194

Composition and morphology control in ordered mesostructured high-temperature ceramics from block copolymer mesophases

Marleen Kamperman, Phong Du, Raluca O. Scarlat, Erik Herz, Ulrike Werner-Zwanziger, Robert Graf, Josef W. Zwanziger, Hans W. Spiess, Ulrich Wiesner^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

23 Citations (Scopus)

Abstract

The co-assembly between a polyisoprene-block-poly(dimethylaminoethyl methacrylate) block copolymer and poly(ureamethylvinyl)silazane is investigated. The hybrid morphology can be controlled by systematically increasing the inorganic-to-organic ratio or by changing the molecular weight of the block copolymer. Temperature treatment up to 1500°C of the hybrids resulted in mesoporous, ordered non-oxide-type ceramics. The results suggest that careful control of co-assembly processes enables access to nanostructured high-temperature ceramics that may have novel mechanical, thermal, and chemical properties.

Original language	English
Pages (from-to)	2096-2108
Number of pages	13
Journal	Macromolecular Chemistry and Physics
Volume	208
Issue number	19-20
DOIs	https://doi.org/10.1002/macp.200700194
Publication status	Published - 24-Oct-2007
Externally published	Yes

Keywords

Block copolymers
High-temperature ceramics
Nanocomposites
Polymer-derived ceramics
Structure-directing agents

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10.1002/macp.200700194

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title = "Composition and morphology control in ordered mesostructured high-temperature ceramics from block copolymer mesophases",

abstract = "The co-assembly between a polyisoprene-block-poly(dimethylaminoethyl methacrylate) block copolymer and poly(ureamethylvinyl)silazane is investigated. The hybrid morphology can be controlled by systematically increasing the inorganic-to-organic ratio or by changing the molecular weight of the block copolymer. Temperature treatment up to 1500°C of the hybrids resulted in mesoporous, ordered non-oxide-type ceramics. The results suggest that careful control of co-assembly processes enables access to nanostructured high-temperature ceramics that may have novel mechanical, thermal, and chemical properties.",

keywords = "Block copolymers, High-temperature ceramics, Nanocomposites, Polymer-derived ceramics, Structure-directing agents",

author = "Marleen Kamperman and Phong Du and Scarlat, {Raluca O.} and Erik Herz and Ulrike Werner-Zwanziger and Robert Graf and Zwanziger, {Josef W.} and Spiess, {Hans W.} and Ulrich Wiesner",

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language = "English",

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T1 - Composition and morphology control in ordered mesostructured high-temperature ceramics from block copolymer mesophases

AU - Kamperman, Marleen

AU - Du, Phong

AU - Scarlat, Raluca O.

AU - Herz, Erik

AU - Werner-Zwanziger, Ulrike

AU - Graf, Robert

AU - Zwanziger, Josef W.

AU - Spiess, Hans W.

AU - Wiesner, Ulrich

PY - 2007/10/24

Y1 - 2007/10/24

N2 - The co-assembly between a polyisoprene-block-poly(dimethylaminoethyl methacrylate) block copolymer and poly(ureamethylvinyl)silazane is investigated. The hybrid morphology can be controlled by systematically increasing the inorganic-to-organic ratio or by changing the molecular weight of the block copolymer. Temperature treatment up to 1500°C of the hybrids resulted in mesoporous, ordered non-oxide-type ceramics. The results suggest that careful control of co-assembly processes enables access to nanostructured high-temperature ceramics that may have novel mechanical, thermal, and chemical properties.

AB - The co-assembly between a polyisoprene-block-poly(dimethylaminoethyl methacrylate) block copolymer and poly(ureamethylvinyl)silazane is investigated. The hybrid morphology can be controlled by systematically increasing the inorganic-to-organic ratio or by changing the molecular weight of the block copolymer. Temperature treatment up to 1500°C of the hybrids resulted in mesoporous, ordered non-oxide-type ceramics. The results suggest that careful control of co-assembly processes enables access to nanostructured high-temperature ceramics that may have novel mechanical, thermal, and chemical properties.

KW - Block copolymers

KW - High-temperature ceramics

KW - Nanocomposites

KW - Polymer-derived ceramics

KW - Structure-directing agents

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DO - 10.1002/macp.200700194

M3 - Article

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SN - 1022-1352

VL - 208

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JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 19-20

ER -

Composition and morphology control in ordered mesostructured high-temperature ceramics from block copolymer mesophases

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Keywords

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