Abstract
Treatment of N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine (L) with Pb(OAc)2/KBr, Cu(acac)2, and Cu(OAc)2 afforded three new coordination polymers [Pb(μ-L)(μ-Br)2]n (1), [Cu(μ-L)(acac)2]n (2), and [Cu2(μ-L)(μ-OAc)4]n (3). These coordination polymers have been structurally characterized by single crystal X-ray diffraction. Compound 1 has a 2D sheet structure in which the lead(II) centers are bridged by both L and bromide ligands. Compound 2 adopts a 1D neutral coordination chain and consists of bis(2,4-pentanedionato) copper(II) units connected by rigid bridging L ligands. The structure of compound 3 also adopts a 1D neutral coordination chain in which two copper centers are connected through four acetate groups to form a Cu(OAc)4Cu paddle-wheel-type cage between two bridging L ligands. The FT-IR spectra, thermal behavior and photoluminescence properties of these coordination polymers have also been investigated.
Original language | English |
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Pages (from-to) | 158-165 |
Number of pages | 8 |
Journal | Inorganica Chimica Acta |
Volume | 455 |
Issue number | 1 |
DOIs | |
Publication status | Published - 30-Jan-2017 |
Keywords
- Coordination polymer
- Dipyridyl ligand
- Photoluminescence property
- Single crystal X-ray diffraction
- Thermal behavior
Datasets
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CCDC 1481783: Experimental Crystal Structure Determination
Shaabani, B. (Contributor), Rad-Yousefnia, N. (Contributor), Zahedi, M. (Contributor), Ertan, Ş. (Contributor), Blake, G. (Contributor) & Zakerhamidi, M. S. (Contributor), University of Groningen, 21-Jun-2016
DOI: 10.5517/ccdc.csd.cc1lqxgp
Dataset
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CCDC 1481155: Experimental Crystal Structure Determination
Shaabani, B. (Contributor), Rad-Yousefnia, N. (Contributor), Zahedi, M. (Contributor), Ertan, Ş. (Contributor), Blake, G. (Contributor) & Zakerhamidi, M. S. (Contributor), University of Groningen, 21-Jun-2016
DOI: 10.5517/ccdc.csd.cc1lq86s
Dataset
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CCDC 1481350: Experimental Crystal Structure Determination
Shaabani, B. (Contributor), Rad-Yousefnia, N. (Contributor), Zahedi, M. (Contributor), Ertan, Ş. (Contributor), Blake, G. (Contributor) & Zakerhamidi, M. S. (Contributor), University of Groningen, 22-May-2016
DOI: 10.5517/ccdc.csd.cc1lqgh8
Dataset