Construction of new 1D and 2D coordination polymers generated from rigid N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine ligand: Syntheses, crystal structures and luminescence properties

Behrouz Shaabani; Negar Rad-Yousefnia; Mansoureh Zahedi; Şahin Ertan; Graeme R. Blake; Mohammad Sadegh Zakerhamidi

doi:10.1016/j.ica.2016.10.021

Construction of new 1D and 2D coordination polymers generated from rigid N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine ligand: Syntheses, crystal structures and luminescence properties

Behrouz Shaabani^*, Negar Rad-Yousefnia, Mansoureh Zahedi, Şahin Ertan, Graeme R. Blake, Mohammad Sadegh Zakerhamidi

^*Corresponding author for this work

Solid State Materials for Electronics

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Treatment of N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine (L) with Pb(OAc)₂/KBr, Cu(acac)₂, and Cu(OAc)₂ afforded three new coordination polymers [Pb(μ-L)(μ-Br)₂]_n (1), [Cu(μ-L)(acac)₂]_n (2), and [Cu₂(μ-L)(μ-OAc)₄]_n (3). These coordination polymers have been structurally characterized by single crystal X-ray diffraction. Compound 1 has a 2D sheet structure in which the lead(II) centers are bridged by both L and bromide ligands. Compound 2 adopts a 1D neutral coordination chain and consists of bis(2,4-pentanedionato) copper(II) units connected by rigid bridging L ligands. The structure of compound 3 also adopts a 1D neutral coordination chain in which two copper centers are connected through four acetate groups to form a Cu(OAc)₄Cu paddle-wheel-type cage between two bridging L ligands. The FT-IR spectra, thermal behavior and photoluminescence properties of these coordination polymers have also been investigated.

Original language	English
Pages (from-to)	158-165
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	455
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2016.10.021
Publication status	Published - 30-Jan-2017

Keywords

Coordination polymer
Dipyridyl ligand
Photoluminescence property
Single crystal X-ray diffraction
Thermal behavior

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10.1016/j.ica.2016.10.021

Construction of new 1D and 2D coordination polymers generated from rigid N,NFinal publisher's version, 1.47 MBLicence: Taverne

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CCDC 1481783: Experimental Crystal Structure Determination
Shaabani, B. (Contributor), Rad-Yousefnia, N. (Contributor), Zahedi, M. (Contributor), Ertan, Ş. (Contributor), Blake, G. (Contributor) & Zakerhamidi, M. S. (Contributor), University of Groningen, 21-Jun-2016
DOI: 10.5517/ccdc.csd.cc1lqxgp
Dataset
CCDC 1481155: Experimental Crystal Structure Determination
Shaabani, B. (Contributor), Rad-Yousefnia, N. (Contributor), Zahedi, M. (Contributor), Ertan, Ş. (Contributor), Blake, G. (Contributor) & Zakerhamidi, M. S. (Contributor), University of Groningen, 21-Jun-2016
DOI: 10.5517/ccdc.csd.cc1lq86s
Dataset
CCDC 1481350: Experimental Crystal Structure Determination
Shaabani, B. (Contributor), Rad-Yousefnia, N. (Contributor), Zahedi, M. (Contributor), Ertan, Ş. (Contributor), Blake, G. (Contributor) & Zakerhamidi, M. S. (Contributor), University of Groningen, 22-May-2016
DOI: 10.5517/ccdc.csd.cc1lqgh8
Dataset

Cite this

Shaabani, B., Rad-Yousefnia, N., Zahedi, M., Ertan, Ş., Blake, G. R., & Zakerhamidi, M. S. (2017). Construction of new 1D and 2D coordination polymers generated from rigid N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine ligand: Syntheses, crystal structures and luminescence properties. Inorganica Chimica Acta, 455(1), 158-165. https://doi.org/10.1016/j.ica.2016.10.021

@article{d53b6465b8c640e4bdcfd025ca3e50a8,

title = "Construction of new 1D and 2D coordination polymers generated from rigid N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine ligand: Syntheses, crystal structures and luminescence properties",

abstract = "Treatment of N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine (L) with Pb(OAc)2/KBr, Cu(acac)2, and Cu(OAc)2 afforded three new coordination polymers [Pb(μ-L)(μ-Br)2]n (1), [Cu(μ-L)(acac)2]n (2), and [Cu2(μ-L)(μ-OAc)4]n (3). These coordination polymers have been structurally characterized by single crystal X-ray diffraction. Compound 1 has a 2D sheet structure in which the lead(II) centers are bridged by both L and bromide ligands. Compound 2 adopts a 1D neutral coordination chain and consists of bis(2,4-pentanedionato) copper(II) units connected by rigid bridging L ligands. The structure of compound 3 also adopts a 1D neutral coordination chain in which two copper centers are connected through four acetate groups to form a Cu(OAc)4Cu paddle-wheel-type cage between two bridging L ligands. The FT-IR spectra, thermal behavior and photoluminescence properties of these coordination polymers have also been investigated.",

keywords = "Coordination polymer, Dipyridyl ligand, Photoluminescence property, Single crystal X-ray diffraction, Thermal behavior",

author = "Behrouz Shaabani and Negar Rad-Yousefnia and Mansoureh Zahedi and {\c S}ahin Ertan and Blake, {Graeme R.} and Zakerhamidi, {Mohammad Sadegh}",

year = "2017",

month = jan,

day = "30",

doi = "10.1016/j.ica.2016.10.021",

language = "English",

volume = "455",

pages = "158--165",

journal = "Inorganica chimica acta-Articles",

issn = "0020-1693",

publisher = "ELSEVIER SCIENCE SA LAUSANNE",

number = "1",

}

Shaabani, B, Rad-Yousefnia, N, Zahedi, M, Ertan, Ş, Blake, GR & Zakerhamidi, MS 2017, 'Construction of new 1D and 2D coordination polymers generated from rigid N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine ligand: Syntheses, crystal structures and luminescence properties', Inorganica Chimica Acta, vol. 455, no. 1, pp. 158-165. https://doi.org/10.1016/j.ica.2016.10.021

Construction of new 1D and 2D coordination polymers generated from rigid N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine ligand : Syntheses, crystal structures and luminescence properties. / Shaabani, Behrouz; Rad-Yousefnia, Negar; Zahedi, Mansoureh et al.

In: Inorganica Chimica Acta, Vol. 455, No. 1, 30.01.2017, p. 158-165.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Construction of new 1D and 2D coordination polymers generated from rigid N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine ligand

T2 - Syntheses, crystal structures and luminescence properties

AU - Shaabani, Behrouz

AU - Rad-Yousefnia, Negar

AU - Zahedi, Mansoureh

AU - Ertan, Şahin

AU - Blake, Graeme R.

AU - Zakerhamidi, Mohammad Sadegh

PY - 2017/1/30

Y1 - 2017/1/30

N2 - Treatment of N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine (L) with Pb(OAc)2/KBr, Cu(acac)2, and Cu(OAc)2 afforded three new coordination polymers [Pb(μ-L)(μ-Br)2]n (1), [Cu(μ-L)(acac)2]n (2), and [Cu2(μ-L)(μ-OAc)4]n (3). These coordination polymers have been structurally characterized by single crystal X-ray diffraction. Compound 1 has a 2D sheet structure in which the lead(II) centers are bridged by both L and bromide ligands. Compound 2 adopts a 1D neutral coordination chain and consists of bis(2,4-pentanedionato) copper(II) units connected by rigid bridging L ligands. The structure of compound 3 also adopts a 1D neutral coordination chain in which two copper centers are connected through four acetate groups to form a Cu(OAc)4Cu paddle-wheel-type cage between two bridging L ligands. The FT-IR spectra, thermal behavior and photoluminescence properties of these coordination polymers have also been investigated.

AB - Treatment of N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine (L) with Pb(OAc)2/KBr, Cu(acac)2, and Cu(OAc)2 afforded three new coordination polymers [Pb(μ-L)(μ-Br)2]n (1), [Cu(μ-L)(acac)2]n (2), and [Cu2(μ-L)(μ-OAc)4]n (3). These coordination polymers have been structurally characterized by single crystal X-ray diffraction. Compound 1 has a 2D sheet structure in which the lead(II) centers are bridged by both L and bromide ligands. Compound 2 adopts a 1D neutral coordination chain and consists of bis(2,4-pentanedionato) copper(II) units connected by rigid bridging L ligands. The structure of compound 3 also adopts a 1D neutral coordination chain in which two copper centers are connected through four acetate groups to form a Cu(OAc)4Cu paddle-wheel-type cage between two bridging L ligands. The FT-IR spectra, thermal behavior and photoluminescence properties of these coordination polymers have also been investigated.

KW - Coordination polymer

KW - Dipyridyl ligand

KW - Photoluminescence property

KW - Single crystal X-ray diffraction

KW - Thermal behavior

U2 - 10.1016/j.ica.2016.10.021

DO - 10.1016/j.ica.2016.10.021

M3 - Article

AN - SCOPUS:84994106421

VL - 455

SP - 158

EP - 165

JO - Inorganica chimica acta-Articles

JF - Inorganica chimica acta-Articles

SN - 0020-1693

IS - 1

ER -

Construction of new 1D and 2D coordination polymers generated from rigid N,N′-bis(4-pyridylmethylene)-1,5-naphthalenediamine ligand: Syntheses, crystal structures and luminescence properties

Abstract

Keywords

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CCDC 1481783: Experimental Crystal Structure Determination

CCDC 1481155: Experimental Crystal Structure Determination

CCDC 1481350: Experimental Crystal Structure Determination

Cite this