CRYSTAL-STRUCTURE AND SILVER ION COMPLEXATION OF A NOVEL PORPHYRAZINE SUBSTITUTED WITH 4 DITHIACROWN ETHER RINGS

CF VANNOSTRUM*, FBG BENNEKER, N VELDMAN, AL SPEK, AJ SCHOUTEN, RJM NOLTE

*Corresponding author for this work

Research output: Contribution to journalComment/Letter to the editorAcademicpeer-review

24 Citations (Scopus)

Abstract

The synthesis of magnesium porphyrazines substituted with sulfur-containing 15-crown-5 and 18-crown-6 macrocycles is reported as well as the single crystal structure of the 18-crown-6 substituted porphyrazine; the larger crown ether compound is shown to form dimers with Ag+ ions, unlike the porphyrazine with the smaller crown ether rings.

Original languageEnglish
Pages (from-to)109-110
Number of pages2
JournalRecueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands Chemical Society
Volume113
Issue number2
Publication statusPublished - Feb-1994

Keywords

  • SUPRAMOLECULAR CHEMISTRY
  • TETRAAZAPORPHYRINE
  • CROWN ETHERS
  • AGGREGATION
  • PHTHALOCYANINES

Cite this