Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidation

Nicola Armenise; Nabil Tahiri; Niek N H M Eisink; Mathieu Denis; Manuel Jäger; Johannes G De Vries; Martin D Witte; Adriaan J Minnaard

doi:10.1039/c5cc08588h

Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidation

Nicola Armenise, Nabil Tahiri, Niek N H M Eisink, Mathieu Denis, Manuel Jäger, Johannes G De Vries, Martin D Witte, Adriaan J Minnaard

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The catalyst palladium/2,9-CD3-phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant.

Original language	English
Pages (from-to)	2189-2191
Number of pages	3
Journal	Chemical communications (Cambridge, England)
Volume	52
Issue number	10
DOIs	https://doi.org/10.1039/c5cc08588h
Publication status	Published - 4-Jan-2016

Keywords

AEROBIC OXIDATION
AQUEOUS SOLVENTS
DEUTERIUM
COMPLEXES
INSIGHTS
DESIGN
CARBON

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10.1039/c5cc08588h

Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidationFinal publisher's version, 1.46 MBLicence: Taverne

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title = "Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidation",

abstract = "The catalyst palladium/2,9-CD3-phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant.",

keywords = "AEROBIC OXIDATION, AQUEOUS SOLVENTS, DEUTERIUM, COMPLEXES, INSIGHTS, DESIGN, CARBON",

author = "Nicola Armenise and Nabil Tahiri and Eisink, {Niek N H M} and Mathieu Denis and Manuel J{\"a}ger and {De Vries}, {Johannes G} and Witte, {Martin D} and Minnaard, {Adriaan J}",

year = "2016",

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doi = "10.1039/c5cc08588h",

language = "English",

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T1 - Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidation

AU - Armenise, Nicola

AU - Tahiri, Nabil

AU - Eisink, Niek N H M

AU - Denis, Mathieu

AU - Jäger, Manuel

AU - De Vries, Johannes G

AU - Witte, Martin D

AU - Minnaard, Adriaan J

PY - 2016/1/4

Y1 - 2016/1/4

N2 - The catalyst palladium/2,9-CD3-phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant.

AB - The catalyst palladium/2,9-CD3-phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant.

KW - AEROBIC OXIDATION

KW - AQUEOUS SOLVENTS

KW - DEUTERIUM

KW - COMPLEXES

KW - INSIGHTS

KW - DESIGN

KW - CARBON

U2 - 10.1039/c5cc08588h

DO - 10.1039/c5cc08588h

M3 - Article

C2 - 26725590

SN - 1359-7345

VL - 52

SP - 2189

EP - 2191

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

IS - 10

ER -

Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidation

Abstract

Keywords

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