TY - JOUR
T1 - Dimerization of organic cyanides ligated to di-eta-5-cyclopentadienylaryltitanium(III)
AU - de Boer, EJM
AU - Teuben, JH
N1 - Relation: http://www.rug.nl/scheikunde/
date_submitted:2005
Rights: University of Groningen. Stratingh Institute
PY - 1978
Y1 - 1978
N2 - Reactions of Cp2TiR (R = C6H5, o-, m-, p-CH3C6H4, CH2C6H5, C6F5, C1) with R′CN (R′ = C6H5, o-CH3C6H4, CH3) have been studied. The products, (Cp2TiR · R′CN)2, identified by chemical and physical methods, form a new class of compounds, in which two Cp2TiR groups are connected by a bridging diimine ligand formed by oxidative coupling of two cyanide ligands via the cyanide carbon atoms. The metal is formally oxidized to titanium(IV).
AB - Reactions of Cp2TiR (R = C6H5, o-, m-, p-CH3C6H4, CH2C6H5, C6F5, C1) with R′CN (R′ = C6H5, o-CH3C6H4, CH3) have been studied. The products, (Cp2TiR · R′CN)2, identified by chemical and physical methods, form a new class of compounds, in which two Cp2TiR groups are connected by a bridging diimine ligand formed by oxidative coupling of two cyanide ligands via the cyanide carbon atoms. The metal is formally oxidized to titanium(IV).
U2 - 10.1016/S0022-328X(00)90931-8
DO - 10.1016/S0022-328X(00)90931-8
M3 - Article
SN - 0022-328X
VL - 153
SP - 53
EP - 57
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -