Dissociation constants and thermodynamic properties of alkanolamines

E. S. Hamborg; G. F. Versteeg

doi:10.1016/j.egypro.2009.01.159

Dissociation constants and thermodynamic properties of alkanolamines

E. S. Hamborg, G. F. Versteeg

Engineering and Technology Institute Groningen

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Abstract

The dissociation constants of protonated 2-amino-2-ethyl-1,3-propanediol (AEPD), 2-amino-2-methyl-1-propanol (AMP), diethylmonoethanolamine (DEMEA), diisopropanolamine (DIPA), dimethylmonoethanolamine (DMMEA), monoethanolamine (MEA), 1-amino-2-propanol (MIPA), and methylmonoethanolamine (MMEA) have been determined by electromotive force measurements from (293 to 353) K. The experimental results and derived values of the standard state thermodynamic properties are reported. © 2009 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1213-1218
Number of pages	6
Journal	Energy Procedia
Volume	1
Issue number	1
DOIs	https://doi.org/10.1016/j.egypro.2009.01.159
Publication status	Published - 2009

Keywords

Protonation
Ionization
Enthalpy
Gibbs free energy
Dissociation
Basic strength
Alkanolamine

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@article{762a2775f6f14648b28ebb5c89313ff5,

title = "Dissociation constants and thermodynamic properties of alkanolamines",

abstract = "The dissociation constants of protonated 2-amino-2-ethyl-1,3-propanediol (AEPD), 2-amino-2-methyl-1-propanol (AMP), diethylmonoethanolamine (DEMEA), diisopropanolamine (DIPA), dimethylmonoethanolamine (DMMEA), monoethanolamine (MEA), 1-amino-2-propanol (MIPA), and methylmonoethanolamine (MMEA) have been determined by electromotive force measurements from (293 to 353) K. The experimental results and derived values of the standard state thermodynamic properties are reported. {\textcopyright} 2009 Elsevier Ltd. All rights reserved.",

keywords = "Protonation, Ionization, Enthalpy, Gibbs free energy, Dissociation, Basic strength, Alkanolamine",

author = "Hamborg, {E. S.} and Versteeg, {G. F.}",

note = "Relation: http://www.rug.nl/fwn/itm Rights: University of Groningen",

year = "2009",

doi = "10.1016/j.egypro.2009.01.159",

language = "English",

volume = "1",

pages = "1213--1218",

journal = "Energy Procedia",

issn = "1876-6102",

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TY - JOUR

T1 - Dissociation constants and thermodynamic properties of alkanolamines

AU - Hamborg, E. S.

AU - Versteeg, G. F.

N1 - Relation: http://www.rug.nl/fwn/itm Rights: University of Groningen

PY - 2009

Y1 - 2009

N2 - The dissociation constants of protonated 2-amino-2-ethyl-1,3-propanediol (AEPD), 2-amino-2-methyl-1-propanol (AMP), diethylmonoethanolamine (DEMEA), diisopropanolamine (DIPA), dimethylmonoethanolamine (DMMEA), monoethanolamine (MEA), 1-amino-2-propanol (MIPA), and methylmonoethanolamine (MMEA) have been determined by electromotive force measurements from (293 to 353) K. The experimental results and derived values of the standard state thermodynamic properties are reported. © 2009 Elsevier Ltd. All rights reserved.

AB - The dissociation constants of protonated 2-amino-2-ethyl-1,3-propanediol (AEPD), 2-amino-2-methyl-1-propanol (AMP), diethylmonoethanolamine (DEMEA), diisopropanolamine (DIPA), dimethylmonoethanolamine (DMMEA), monoethanolamine (MEA), 1-amino-2-propanol (MIPA), and methylmonoethanolamine (MMEA) have been determined by electromotive force measurements from (293 to 353) K. The experimental results and derived values of the standard state thermodynamic properties are reported. © 2009 Elsevier Ltd. All rights reserved.

KW - Protonation

KW - Ionization

KW - Enthalpy

KW - Gibbs free energy

KW - Dissociation

KW - Basic strength

KW - Alkanolamine

U2 - 10.1016/j.egypro.2009.01.159

DO - 10.1016/j.egypro.2009.01.159

M3 - Article

SN - 1876-6102

VL - 1

SP - 1213

EP - 1218

JO - Energy Procedia

JF - Energy Procedia

IS - 1

ER -