Dynamic control over catalytic function using responsive bisthiourea catalysts

M. Vlatkovic; J. Volaric; B. S. L. Collins; L. Bernardi; B. L. Feringa

doi:10.1039/c7ob01851g

Dynamic control over catalytic function using responsive bisthiourea catalysts

M. Vlatkovic, J. Volaric, B. S. L. Collins, L. Bernardi, B. L. Feringa^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

17 Citations (Scopus)

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Abstract

Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.

Original language	English
Pages (from-to)	8285-8294
Number of pages	10
Journal	Organic & Biomolecular Chemistry
Volume	15
Issue number	39
DOIs	https://doi.org/10.1039/c7ob01851g
Publication status	Published - 21-Oct-2017

Keywords

BAYLIS-HILLMAN REACTION
ENANTIOSELECTIVE HENRY REACTIONS
NITROALDOL REACTION
MOLECULAR MOTORS
ORGANOCATALYSTS
LIGHT
RESOLUTION
PHOSPHINE
LIGANDS
SYSTEMS

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Dynamic control over catalytic function using responsive bisthiourea catalystsFinal publisher's version, 2.92 MBLicence: Taverne

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title = "Dynamic control over catalytic function using responsive bisthiourea catalysts",

abstract = "Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.",

keywords = "BAYLIS-HILLMAN REACTION, ENANTIOSELECTIVE HENRY REACTIONS, NITROALDOL REACTION, MOLECULAR MOTORS, ORGANOCATALYSTS, LIGHT, RESOLUTION, PHOSPHINE, LIGANDS, SYSTEMS",

author = "M. Vlatkovic and J. Volaric and Collins, {B. S. L.} and L. Bernardi and Feringa, {B. L.}",

year = "2017",

month = oct,

day = "21",

doi = "10.1039/c7ob01851g",

language = "English",

volume = "15",

pages = "8285--8294",

journal = "Organic & Biomolecular Chemistry",

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publisher = "ROYAL SOC CHEMISTRY",

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TY - JOUR

T1 - Dynamic control over catalytic function using responsive bisthiourea catalysts

AU - Vlatkovic, M.

AU - Volaric, J.

AU - Collins, B. S. L.

AU - Bernardi, L.

AU - Feringa, B. L.

PY - 2017/10/21

Y1 - 2017/10/21

N2 - Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.

AB - Two novel bisthiourea molecular motor-based catalysts were designed and their dynamic control of activity and stereoselectivity in the Henry reaction using heat and light as external stimuli was investigated. Enantioselective organocatalysis studies established that a basic functional group is not required within the catalyst core to effect efficient dual stereocontrol, illustrating novel stimuli responsive organocatalysts.

KW - BAYLIS-HILLMAN REACTION

KW - ENANTIOSELECTIVE HENRY REACTIONS

KW - NITROALDOL REACTION

KW - MOLECULAR MOTORS

KW - ORGANOCATALYSTS

KW - LIGHT

KW - RESOLUTION

KW - PHOSPHINE

KW - LIGANDS

KW - SYSTEMS

U2 - 10.1039/c7ob01851g

DO - 10.1039/c7ob01851g

M3 - Article

SN - 1477-0520

VL - 15

SP - 8285

EP - 8294

JO - Organic & Biomolecular Chemistry

JF - Organic & Biomolecular Chemistry

IS - 39

ER -

Dynamic control over catalytic function using responsive bisthiourea catalysts

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Keywords

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