Abstract
Monodentate phosphoramidites, in particular PipPhos and its octahydro analogue, are excellent ligands for the rhodium-catalyzed asymmetric hydrogenation of aromatic enol acetates, enol carbamates, and 2-dienol carbamates up to 98% ee. These latter substrates were hydrogenated selectively to the carbamates of the allyl alcohol.
| Original language | English |
|---|---|
| Pages (from-to) | 4177-4180 |
| Number of pages | 4 |
| Journal | Organic letters |
| Volume | 7 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - 15-Sept-2005 |
Keywords
- ASYMMETRIC HYDROGENATION
- PHOSPHORUS LIGANDS
- PHOSPHITE LIGANDS
- COMPLEXES
- ACID
- DERIVATIVES
- CARBONATES
- OLEFINS
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