Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers: Copper/Phosphoramidite-Catalyzed Allylic Alkylation with Organolithium Reagents

Martin Fananas Mastral; Manuel Perez; Pieter H. Bos; Alena Rudolph; Syuzanna R. Harutyunyan; Ben L. Feringa

doi:10.1002/anie.201107840

Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers: Copper/Phosphoramidite-Catalyzed Allylic Alkylation with Organolithium Reagents

Martin Fananas Mastral, Manuel Perez , Pieter H. Bos, Alena Rudolph, Syuzanna R. Harutyunyan^*, Ben L. Feringa

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

59 Citations (Scopus)

Original language	English
Pages (from-to)	1922-1925
Number of pages	4
Journal	Angewandte Chemie-International Edition
Volume	51
Issue number	8
DOIs	https://doi.org/10.1002/anie.201107840
Publication status	Published - 2012

Keywords

allylic compounds
copper
ligand effects
organolithium reagents
synthetic methods
ASYMMETRIC ADDITION
GRIGNARD-REAGENTS
CONJUGATE ADDITION
VINYLALUMINUM REAGENTS
S(N)2' SUBSTITUTIONS
METATHESIS
ALKYLZINC
ALDEHYDES
EFFICIENT
LIGANDS

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Cite this

@article{dcf5b1aac46f4cb08ef8412d05b36d17,

title = "Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers: Copper/Phosphoramidite-Catalyzed Allylic Alkylation with Organolithium Reagents",

keywords = "allylic compounds, copper, ligand effects, organolithium reagents, synthetic methods, ASYMMETRIC ADDITION, GRIGNARD-REAGENTS, CONJUGATE ADDITION, VINYLALUMINUM REAGENTS, S(N)2' SUBSTITUTIONS, METATHESIS, ALKYLZINC, ALDEHYDES, EFFICIENT, LIGANDS",

author = "{Fananas Mastral}, Martin and Manuel Perez and Bos, {Pieter H.} and Alena Rudolph and Harutyunyan, {Syuzanna R.} and Feringa, {Ben L.}",

note = "PT: J; TC: 2; UT: WOS:000300446100034",

year = "2012",

doi = "10.1002/anie.201107840",

language = "English",

volume = "51",

pages = "1922--1925",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "WILEY-V C H VERLAG GMBH",

number = "8",

}

Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers : Copper/Phosphoramidite-Catalyzed Allylic Alkylation with Organolithium Reagents. / Fananas Mastral, Martin; Perez , Manuel; Bos, Pieter H. et al.

In: Angewandte Chemie-International Edition, Vol. 51, No. 8, 2012, p. 1922-1925.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers

T2 - Copper/Phosphoramidite-Catalyzed Allylic Alkylation with Organolithium Reagents

AU - Fananas Mastral, Martin

AU - Perez , Manuel

AU - Bos, Pieter H.

AU - Rudolph, Alena

AU - Harutyunyan, Syuzanna R.

AU - Feringa, Ben L.

N1 - PT: J; TC: 2; UT: WOS:000300446100034

PY - 2012

Y1 - 2012

KW - allylic compounds

KW - copper

KW - ligand effects

KW - organolithium reagents

KW - synthetic methods

KW - ASYMMETRIC ADDITION

KW - GRIGNARD-REAGENTS

KW - CONJUGATE ADDITION

KW - VINYLALUMINUM REAGENTS

KW - S(N)2' SUBSTITUTIONS

KW - METATHESIS

KW - ALKYLZINC

KW - ALDEHYDES

KW - EFFICIENT

KW - LIGANDS

U2 - 10.1002/anie.201107840

DO - 10.1002/anie.201107840

M3 - Article

VL - 51

SP - 1922

EP - 1925

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 8

ER -