Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(IV)=O species

Tieme A. van den Berg; Johannes W. de Boer; Wesley R. Browne; Gerard Roelfes; Bernard Feringa

doi:10.1039/b412016g

Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(IV)=O species

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Abstract

Catalytic alkane oxidation with high selectivity using peracids and an (N4Py)Fe complex is presented and the role of [(N4Py)Fe(IV)=O]2+ species, molecular oxygen and hydroxyl radicals in the catalysis is discussed.

Original language	English
Pages (from-to)	2550 - 2551
Number of pages	2
Journal	Chemical Communications
Volume	43
Issue number	22
DOIs	https://doi.org/10.1039/b412016g
Publication status	Published - 2004

Keywords

MODELS
INTERMEDIATE
EPOXIDATION
ACTIVATION
COMPLEXES

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2004ChemCommvdBergSupp.pdfFinal publisher's version, 177 KB
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title = "Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(IV)=O species",

abstract = "Catalytic alkane oxidation with high selectivity using peracids and an (N4Py)Fe complex is presented and the role of [(N4Py)Fe(IV)=O]2+ species, molecular oxygen and hydroxyl radicals in the catalysis is discussed.",

keywords = "MODELS, INTERMEDIATE, EPOXIDATION, ACTIVATION, COMPLEXES",

author = "Berg, \{Tieme A. van den\} and Boer, \{Johannes W. de\} and Browne, \{Wesley R.\} and Gerard Roelfes and Bernard Feringa",

note = "Relation: http://www.rug.nl/scheikunde/ date\_submitted:2005 Rights: University of Groningen. Stratingh Institute",

year = "2004",

doi = "10.1039/b412016g",

language = "English",

volume = "43",

pages = "2550 -- 2551",

journal = "Chemical Communications",

publisher = "ROYAL SOC CHEMISTRY",

number = "22",

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TY - JOUR

T1 - Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids

T2 - evidence for involvement of Fe(IV)=O species

AU - Berg, Tieme A. van den

AU - Boer, Johannes W. de

AU - Browne, Wesley R.

AU - Roelfes, Gerard

AU - Feringa, Bernard

N1 - Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute

PY - 2004

Y1 - 2004

N2 - Catalytic alkane oxidation with high selectivity using peracids and an (N4Py)Fe complex is presented and the role of [(N4Py)Fe(IV)=O]2+ species, molecular oxygen and hydroxyl radicals in the catalysis is discussed.

AB - Catalytic alkane oxidation with high selectivity using peracids and an (N4Py)Fe complex is presented and the role of [(N4Py)Fe(IV)=O]2+ species, molecular oxygen and hydroxyl radicals in the catalysis is discussed.

KW - MODELS

KW - INTERMEDIATE

KW - EPOXIDATION

KW - ACTIVATION

KW - COMPLEXES

U2 - 10.1039/b412016g

DO - 10.1039/b412016g

M3 - Article

VL - 43

SP - 2550

EP - 2551

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(IV)=O species

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Keywords

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