Ferromagnetism and increased ionicity in epitaxially grown TbMnO3 films

D. Rubi; C. de Graaf; C. J. M. Daumont; D. Mannix; R Broer; B Noheda

doi:10.1103/PhysRevB.79.014416

Ferromagnetism and increased ionicity in epitaxially grown TbMnO3 films

D. Rubi^*, C. de Graaf, C. J. M. Daumont, D. Mannix, R Broer, B Noheda

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Thin films of TbMnO3 have been grown on SrTiO3 substrates. The films grow under compressive strain and are only partially clamped to the substrate. This produces remarkable changes in the magnetic properties and, unlike the bulk material, the films display ferromagnetic interactions below the ordering temperature of similar to 40 K. X-ray photoemission measurements in the films show that the Mn 3s splitting is 0.3 eV larger than that of the bulk. Ab initio embedded-cluster calculations yield Mn 3s splittings that are in agreement with the experiment and reveal that the larger observed values are due to a larger ionicity of the films.

Original language	English
Article number	014416
Number of pages	5
Journal	Physical Review. B: Condensed Matter and Materials Physics
Volume	79
Issue number	1
DOIs	https://doi.org/10.1103/PhysRevB.79.014416
Publication status	Published - 13-Jan-2009

Keywords

ab initio calculations
Curie temperature
ferromagnetic materials
magnetic thin films
photoemission
pulsed laser deposition
strontium compounds
terbium compounds
X-ray photoelectron spectra
TRANSITION-METALS
THIN-FILMS
DISTORTION
STATES
DY

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61 Citations
1 Erratum

Erratum: Ferromagnetism and increased ionicity in epitaxially grown TbMnO3 films [Phys. Rev. B 79, 014416 (2009)]
Rubi, D., de Graaf, C., Daumont, C. J. M., Mannix, D., Broer, R. & Noheda, B., Mar-2009, In: Physical Review. B: Condensed Matter and Materials Physics. 79, 10, 1 p., 109901.
Research output: Contribution to journal › Erratum

Cite this

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title = "Ferromagnetism and increased ionicity in epitaxially grown TbMnO3 films",

abstract = "Thin films of TbMnO3 have been grown on SrTiO3 substrates. The films grow under compressive strain and are only partially clamped to the substrate. This produces remarkable changes in the magnetic properties and, unlike the bulk material, the films display ferromagnetic interactions below the ordering temperature of similar to 40 K. X-ray photoemission measurements in the films show that the Mn 3s splitting is 0.3 eV larger than that of the bulk. Ab initio embedded-cluster calculations yield Mn 3s splittings that are in agreement with the experiment and reveal that the larger observed values are due to a larger ionicity of the films.",

keywords = "ab initio calculations, Curie temperature, ferromagnetic materials, magnetic thin films, photoemission, pulsed laser deposition, strontium compounds, terbium compounds, X-ray photoelectron spectra, TRANSITION-METALS, THIN-FILMS, DISTORTION, STATES, DY",

author = "D. Rubi and {de Graaf}, C. and Daumont, {C. J. M.} and D. Mannix and R Broer and B Noheda",

year = "2009",

month = jan,

day = "13",

doi = "10.1103/PhysRevB.79.014416",

language = "English",

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journal = "Physical Review. B: Condensed Matter and Materials Physics",

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TY - JOUR

T1 - Ferromagnetism and increased ionicity in epitaxially grown TbMnO3 films

AU - Rubi, D.

AU - de Graaf, C.

AU - Daumont, C. J. M.

AU - Mannix, D.

AU - Broer, R

AU - Noheda, B

PY - 2009/1/13

Y1 - 2009/1/13

N2 - Thin films of TbMnO3 have been grown on SrTiO3 substrates. The films grow under compressive strain and are only partially clamped to the substrate. This produces remarkable changes in the magnetic properties and, unlike the bulk material, the films display ferromagnetic interactions below the ordering temperature of similar to 40 K. X-ray photoemission measurements in the films show that the Mn 3s splitting is 0.3 eV larger than that of the bulk. Ab initio embedded-cluster calculations yield Mn 3s splittings that are in agreement with the experiment and reveal that the larger observed values are due to a larger ionicity of the films.

AB - Thin films of TbMnO3 have been grown on SrTiO3 substrates. The films grow under compressive strain and are only partially clamped to the substrate. This produces remarkable changes in the magnetic properties and, unlike the bulk material, the films display ferromagnetic interactions below the ordering temperature of similar to 40 K. X-ray photoemission measurements in the films show that the Mn 3s splitting is 0.3 eV larger than that of the bulk. Ab initio embedded-cluster calculations yield Mn 3s splittings that are in agreement with the experiment and reveal that the larger observed values are due to a larger ionicity of the films.

KW - ab initio calculations

KW - Curie temperature

KW - ferromagnetic materials

KW - magnetic thin films

KW - photoemission

KW - pulsed laser deposition

KW - strontium compounds

KW - terbium compounds

KW - X-ray photoelectron spectra

KW - TRANSITION-METALS

KW - THIN-FILMS

KW - DISTORTION

KW - STATES

KW - DY

U2 - 10.1103/PhysRevB.79.014416

DO - 10.1103/PhysRevB.79.014416

M3 - Article

SN - 0163-1829

VL - 79

JO - Physical Review. B: Condensed Matter and Materials Physics

JF - Physical Review. B: Condensed Matter and Materials Physics

IS - 1

M1 - 014416

ER -

Ferromagnetism and increased ionicity in epitaxially grown TbMnO3 films

Abstract

Keywords

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Research output

Erratum: Ferromagnetism and increased ionicity in epitaxially grown TbMnO3 films [Phys. Rev. B 79, 014416 (2009)]

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