Formation and structure of the oxygen-centered lead thiolate cluster Pb5O(SRF)(8)center dot 2C(7)H(8) [R-F=2,4,6-tris(trifluoromethyl)phenyl]

FT Edelmann*, JKF Buijink, SA Brooker, R Herbst-Irmer, U Kilimann, FM Bohnen

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

14 Citations (Scopus)

Abstract

The unusual pentanuclear lead thiolate cluster PbsO(SRF)(8).C2H8 (3) (C7H8 = toluene) has been obtained by oxidation of Pb(SRF)(2) (2) with dry air and structurally characterized. The central oxygen atom is coordinated to three lead atoms in a trigonal planar fashion. The coordination sphere of the other two lead atoms is completed by coordination of toluene molecules.

Original languageEnglish
Pages (from-to)6134-+
Number of pages3
JournalInorganic Chemistry
Volume39
Issue number26
DOIs
Publication statusPublished - 25-Dec-2000

Keywords

  • CRYSTAL-STRUCTURE
  • COMPLEXES
  • PB
  • NONAFLUOROMESITYL
  • DIARYLSTANNYLENE
  • CHEMISTRY
  • TIN(II)
  • SN

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