Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond

Laura Nunes Dos Santos Comprido; Johannes E.M.N. Klein; Gerald Knizia; Johannes Kästner; A. Stephen K. Hashmi

doi:10.1002/chem.201504511

Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond

Laura Nunes Dos Santos Comprido, Johannes E.M.N. Klein, Gerald Knizia, Johannes Kästner, A. Stephen K. Hashmi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

63 Citations (Scopus)

Abstract

We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.

Original language	English
Pages (from-to)	2892-2895
Number of pages	4
Journal	Chemistry - A European Journal
Volume	22
Issue number	9
DOIs	https://doi.org/10.1002/chem.201504511
Publication status	Published - 24-Feb-2016
Externally published	Yes

Keywords

carbene
computational chemistry
gold
vinylidene

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title = "Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond",

abstract = "We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.",

keywords = "carbene, computational chemistry, gold, vinylidene",

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year = "2016",

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AU - Nunes Dos Santos Comprido, Laura

AU - Klein, Johannes E.M.N.

AU - Knizia, Gerald

AU - Kästner, Johannes

AU - Hashmi, A. Stephen K.

PY - 2016/2/24

Y1 - 2016/2/24

N2 - We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.

AB - We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.

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KW - computational chemistry

KW - gold

KW - vinylidene

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DO - 10.1002/chem.201504511

M3 - Article

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

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Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond

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