Green mediated sol-gel synthesis of M_xCu_1-xO (M = La,Ce x = 0.02–0.06) as an efficient catalyst for electrocatalytic oxygen evolution reaction

The imperative for advancing contemporary human society lies in the essential requirement to create energy generation systems that are sustainable, environmentally friendly, and exceptionally efficient. The development of efficient electrocatalysts, that are environmentally benign, economically viable and easily available, for alkaline oxygen evolution reaction is a significant research area in this regard. The present study focuses on a green mediated sol–gel auto-combustion process for the synthesis of lanthanum and cerium doped copper oxide nanoparticles with excellent electrocatalytic activity. Citric acid and polyols enriched lemon juice serves as the medium for the synthesis of various metal doped copper oxide nanoparticles. The extensive electrochemical studies using these catalysts reveals that, among the various doped samples, 5% lanthanum and 5% cerium doped catalysts exhibited the best performance in oxygen evolution reaction. Doping was found to enhance electrical conductivity and create oxygen vacancies, which enhanced the electrocatalytic activity of the catalysts. Specifically, the 5% lanthanum-doped copper oxide showed an overpotential of 340 mV, while the cerium-doped material exhibited an overpotential of 337 mV at a current density of 10 mA cm⁻² in 1 M KOH. Moreover, the lanthanum-doped sample displayed a Tafel slope of 49 mV dec⁻¹, whereas the cerium-doped sample had a Tafel slope of 60 mV dec⁻¹ with better durability. Additionally, the chronopotentiometric studies revels the stability and long-term performance of LCO5 and CCO5, maintaining consistent potential of 1.58 V throughout 5 h at a current density of 10 mA cm⁻². This study is conclusive evidence that the incorporation of rare earth elements improves the conductivity and overpotential of pristine copper oxide nanoparticles, making them highly effective in the oxygen evolution reactions.