High Energy Resolution Fluorescence Detection X‐Ray Absorption Spectroscopy: Detection of Adsorption Sites in Supported Metal Catalysts

Moniek Tromp; Jeroen A. Van Bokhoven; Olga V. Safonova; Frank M.F. De Groot; John Evans; Pieter Glatzel

doi:10.1063/1.2644620

High Energy Resolution Fluorescence Detection X‐Ray Absorption Spectroscopy: Detection of Adsorption Sites in Supported Metal Catalysts

Moniek Tromp^*
, Jeroen A. Van Bokhoven
, Olga V. Safonova
, Frank M.F. De Groot
, John Evans
, Pieter Glatzel

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

8 Citations (Scopus)

Abstract

High energy resolution fluorescence detection (HERFD) X-ray adsorption spectroscopy (XAS) is demonstrated as a new tool to identify the geometry of metal adsorption sites and the orbitals involved in bonding. The type of CO adsorption site on a nanoparticular Pt-Al₂O₃ catalyst is determined. The orbitals involved in the Pt - CO bonding are identified using theoretical FEFF8.0 calculations. In situ application of HERFD XAS is applicable to a large number of catalytic systems and will provide fundamental insights in structure - performance relationships.

Original language	English
Title of host publication	X-RAY ABSORPTION FINE STRUCTURE - XAFS13
Subtitle of host publication	13th International Conference
Publisher	AIP PRESS
Pages	651-653
Number of pages	3
ISBN (Print)	9780735403840
DOIs	https://doi.org/10.1063/1.2644620
Publication status	Published - 26-Mar-2007
Externally published	Yes
Event	X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference - Stanford, CA, United States Duration: 9-Jul-2006 → 14-Jul-2006

Publication series

Name	AIP Conference Proceedings
Volume	882
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference
Country/Territory	United States
City	Stanford, CA
Period	09/07/2006 → 14/07/2006

Keywords

CO adsorption
HERFD XAS
High energy resolution
In situ
XANES

Access to Document

10.1063/1.2644620

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Tromp, M., Van Bokhoven, J. A., Safonova, O. V., De Groot, F. M. F., Evans, J., & Glatzel, P. (2007). High Energy Resolution Fluorescence Detection X‐Ray Absorption Spectroscopy: Detection of Adsorption Sites in Supported Metal Catalysts. In X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference (pp. 651-653). (AIP Conference Proceedings; Vol. 882). AIP PRESS. https://doi.org/10.1063/1.2644620

@inproceedings{81c22f43a8a24a0c8beca52e3a28506a,

title = "High Energy Resolution Fluorescence Detection X‐Ray Absorption Spectroscopy: Detection of Adsorption Sites in Supported Metal Catalysts",

abstract = "High energy resolution fluorescence detection (HERFD) X-ray adsorption spectroscopy (XAS) is demonstrated as a new tool to identify the geometry of metal adsorption sites and the orbitals involved in bonding. The type of CO adsorption site on a nanoparticular Pt-Al2O3 catalyst is determined. The orbitals involved in the Pt - CO bonding are identified using theoretical FEFF8.0 calculations. In situ application of HERFD XAS is applicable to a large number of catalytic systems and will provide fundamental insights in structure - performance relationships.",

keywords = "CO adsorption, HERFD XAS, High energy resolution, In situ, XANES",

author = "Moniek Tromp and \{Van Bokhoven\}, \{Jeroen A.\} and Safonova, \{Olga V.\} and \{De Groot\}, \{Frank M.F.\} and John Evans and Pieter Glatzel",

year = "2007",

month = mar,

day = "26",

doi = "10.1063/1.2644620",

language = "English",

isbn = "9780735403840",

series = "AIP Conference Proceedings",

publisher = "AIP PRESS",

pages = "651--653",

booktitle = "X-RAY ABSORPTION FINE STRUCTURE - XAFS13",

note = "X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference ; Conference date: 09-07-2006 Through 14-07-2006",

}

Tromp, M, Van Bokhoven, JA, Safonova, OV, De Groot, FMF, Evans, J & Glatzel, P 2007, High Energy Resolution Fluorescence Detection X‐Ray Absorption Spectroscopy: Detection of Adsorption Sites in Supported Metal Catalysts. in X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference. AIP Conference Proceedings, vol. 882, AIP PRESS, pp. 651-653, X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference, Stanford, CA, United States, 09/07/2006. https://doi.org/10.1063/1.2644620

High Energy Resolution Fluorescence Detection X‐Ray Absorption Spectroscopy: Detection of Adsorption Sites in Supported Metal Catalysts. / Tromp, Moniek; Van Bokhoven, Jeroen A.; Safonova, Olga V. et al.
X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference. AIP PRESS, 2007. p. 651-653 (AIP Conference Proceedings; Vol. 882).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

TY - GEN

T1 - High Energy Resolution Fluorescence Detection X‐Ray Absorption Spectroscopy

T2 - X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference

AU - Tromp, Moniek

AU - Van Bokhoven, Jeroen A.

AU - Safonova, Olga V.

AU - De Groot, Frank M.F.

AU - Evans, John

AU - Glatzel, Pieter

PY - 2007/3/26

Y1 - 2007/3/26

N2 - High energy resolution fluorescence detection (HERFD) X-ray adsorption spectroscopy (XAS) is demonstrated as a new tool to identify the geometry of metal adsorption sites and the orbitals involved in bonding. The type of CO adsorption site on a nanoparticular Pt-Al2O3 catalyst is determined. The orbitals involved in the Pt - CO bonding are identified using theoretical FEFF8.0 calculations. In situ application of HERFD XAS is applicable to a large number of catalytic systems and will provide fundamental insights in structure - performance relationships.

AB - High energy resolution fluorescence detection (HERFD) X-ray adsorption spectroscopy (XAS) is demonstrated as a new tool to identify the geometry of metal adsorption sites and the orbitals involved in bonding. The type of CO adsorption site on a nanoparticular Pt-Al2O3 catalyst is determined. The orbitals involved in the Pt - CO bonding are identified using theoretical FEFF8.0 calculations. In situ application of HERFD XAS is applicable to a large number of catalytic systems and will provide fundamental insights in structure - performance relationships.

KW - CO adsorption

KW - HERFD XAS

KW - High energy resolution

KW - In situ

KW - XANES

UR - https://www.scopus.com/pages/publications/33947407187

U2 - 10.1063/1.2644620

DO - 10.1063/1.2644620

M3 - Conference contribution

AN - SCOPUS:33947407187

SN - 9780735403840

T3 - AIP Conference Proceedings

SP - 651

EP - 653

BT - X-RAY ABSORPTION FINE STRUCTURE - XAFS13

PB - AIP PRESS

Y2 - 9 July 2006 through 14 July 2006

ER -

High Energy Resolution Fluorescence Detection X‐Ray Absorption Spectroscopy: Detection of Adsorption Sites in Supported Metal Catalysts

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