Hybrid Catalysts as Lewis Acid

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Abstract

Lewis acid catalysis is undisputedly of great significance for synthetic chemistry. Hence, many hybrid catalysts have been designed that can function as Lewis acid. These hybrid catalysts are based on DNA, protein, or peptide scaffolds. In this chapter an overview of the hybrid catalysts reported for three important classes of Lewis acid-catalyzed reactions is given: C-C bond-forming reactions, C-X bond-forming reactions, and hydrolysis reactions.

Original languageEnglish
Title of host publicationArtificial Metalloenzymes and MetalloDNAzymes in Catalysis
Subtitle of host publicationfrom Design to Applications
EditorsMontserrat Diéguez, Jan-E. Bäckvall, Oscar Pàmies
PublisherWiley-Blackwell
Chapter8
Pages225-251
Number of pages27
Edition1
ISBN (Electronic)9783527804085
ISBN (Print)9783527341788
DOIs
Publication statusPublished - 14-May-2018

Keywords

  • artificial metalloenzymes
  • asymmetric catalysis
  • enzyme design
  • hybrid catalysis
  • Lewis acids

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