Hydrazone-based boron difluoride complexes as triplet photosensitizers for singlet oxygen generation

Sven van Vliet; Johannes G.H. Hermens; Youxin Fu; Lukas Pfeifer; Ben L. Feringa

doi:10.1039/d2cc05336e

Hydrazone-based boron difluoride complexes as triplet photosensitizers for singlet oxygen generation

Sven van Vliet, Johannes G.H. Hermens, Youxin Fu, Lukas Pfeifer, Ben L. Feringa^*

^*Corresponding author for this work

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Abstract

Due to the highly selective nature of singlet oxygen as an oxidant, it has received considerable interest in various areas of (organic) chemistry. Two green light activated hydrazone-based boron difluoride triplet photosensitizers possessing high quantum yields for ¹O₂ formation are reported. These photostable complexes are promising in applications in synthesis and catalysis.

Original language	English
Pages (from-to)	884–887
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	7
Early online date	20-Dec-2022
DOIs	https://doi.org/10.1039/d2cc05336e
Publication status	Published - 21-Jan-2023

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10.1039/d2cc05336eLicence: CC BY-NC

Hydrazone-based boron difluoride complexes as triplet photosensitizers for singlet oxygen generationFinal publisher's version, 1.47 MBLicence: CC BY-NC

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title = "Hydrazone-based boron difluoride complexes as triplet photosensitizers for singlet oxygen generation",

abstract = "Due to the highly selective nature of singlet oxygen as an oxidant, it has received considerable interest in various areas of (organic) chemistry. Two green light activated hydrazone-based boron difluoride triplet photosensitizers possessing high quantum yields for 1O2 formation are reported. These photostable complexes are promising in applications in synthesis and catalysis.",

author = "{van Vliet}, Sven and Hermens, {Johannes G.H.} and Youxin Fu and Lukas Pfeifer and Feringa, {Ben L.}",

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AU - van Vliet, Sven

AU - Hermens, Johannes G.H.

AU - Fu, Youxin

AU - Pfeifer, Lukas

AU - Feringa, Ben L.

PY - 2023/1/21

Y1 - 2023/1/21

N2 - Due to the highly selective nature of singlet oxygen as an oxidant, it has received considerable interest in various areas of (organic) chemistry. Two green light activated hydrazone-based boron difluoride triplet photosensitizers possessing high quantum yields for 1O2 formation are reported. These photostable complexes are promising in applications in synthesis and catalysis.

AB - Due to the highly selective nature of singlet oxygen as an oxidant, it has received considerable interest in various areas of (organic) chemistry. Two green light activated hydrazone-based boron difluoride triplet photosensitizers possessing high quantum yields for 1O2 formation are reported. These photostable complexes are promising in applications in synthesis and catalysis.

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U2 - 10.1039/d2cc05336e

DO - 10.1039/d2cc05336e

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C2 - 36594230

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SN - 1359-7345

VL - 59

SP - 884

EP - 887

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

Hydrazone-based boron difluoride complexes as triplet photosensitizers for singlet oxygen generation

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CCDC 2209988: Experimental Crystal Structure Determination

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Hydrazone-based boron difluoride complexes as triplet photosensitizers for singlet oxygen generation

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CCDC 2209988: Experimental Crystal Structure Determination

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