Infrared spectrum of H2O matrix isolated in CO at 10 K: Evidence for bifurcated dimers

W. Hagen; A. G. G. M. Tielens

doi:10.1063/1.442648

Infrared spectrum of H2O matrix isolated in CO at 10 K: Evidence for bifurcated dimers

W. Hagen, A. G. G. M. Tielens

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Abstract

The spectrum of H2O in a CO matrix is qualitatively different from that of H2O in other matrices. Not only are the frequency shifts of the monomeric absorptions with respect to the gas phase larger than in any other matrix, the pattern of the dimeric absorptions is also markedly different. It is concluded that the H2O dimer in a CO matrix has a bifurcated structure. A number of absorptions due to CO strongly interacting with H2O are also reported.

Original language	English
Pages (from-to)	4198-4207
Number of pages	10
Journal	Journal of Chemical Physics
Volume	75
Issue number	9
DOIs	https://doi.org/10.1063/1.442648
Publication status	Published - 1981
Externally published	Yes

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title = "Infrared spectrum of H2O matrix isolated in CO at 10 K: Evidence for bifurcated dimers",

abstract = "The spectrum of H2O in a CO matrix is qualitatively different from that of H2O in other matrices. Not only are the frequency shifts of the monomeric absorptions with respect to the gas phase larger than in any other matrix, the pattern of the dimeric absorptions is also markedly different. It is concluded that the H2O dimer in a CO matrix has a bifurcated structure. A number of absorptions due to CO strongly interacting with H2O are also reported.",

author = "W. Hagen and Tielens, {A. G. G. M.}",

year = "1981",

doi = "10.1063/1.442648",

language = "English",

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T1 - Infrared spectrum of H2O matrix isolated in CO at 10 K: Evidence for bifurcated dimers

AU - Hagen, W.

AU - Tielens, A. G. G. M.

PY - 1981

Y1 - 1981

N2 - The spectrum of H2O in a CO matrix is qualitatively different from that of H2O in other matrices. Not only are the frequency shifts of the monomeric absorptions with respect to the gas phase larger than in any other matrix, the pattern of the dimeric absorptions is also markedly different. It is concluded that the H2O dimer in a CO matrix has a bifurcated structure. A number of absorptions due to CO strongly interacting with H2O are also reported.

AB - The spectrum of H2O in a CO matrix is qualitatively different from that of H2O in other matrices. Not only are the frequency shifts of the monomeric absorptions with respect to the gas phase larger than in any other matrix, the pattern of the dimeric absorptions is also markedly different. It is concluded that the H2O dimer in a CO matrix has a bifurcated structure. A number of absorptions due to CO strongly interacting with H2O are also reported.

U2 - 10.1063/1.442648

DO - 10.1063/1.442648

M3 - Article

SN - 0021-9606

VL - 75

SP - 4198

EP - 4207

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 9

ER -

Infrared spectrum of H2O matrix isolated in CO at 10 K: Evidence for bifurcated dimers

Abstract

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