Abstract
The extent to which the properties of neutral solutes in dilute aqueous solution deviate from ideal can be related to pairwise Gibbs energy interaction parameters. These pairwise interaction parameters can be re-expressed in terms of group-group interaction parameters. Extension of these concepts to solute-initial state and solute-transition state interactions is reviewed in the context of understanding the effect of added solutes on rate constants for ester hydrolysis in aqueous
solutions. Examples of application of the method of data analysis is reviewed and their significance discussed.
| Original language | English |
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| Number of pages | 6 |
| Journal | Journal of the Chemical Society%2C Perkin Transactions 2 |
| Volume | 11 |
| Issue number | 7 |
| Publication status | Published - 1995 |