Interaction between poly(vinyl pyridine) and poly(2,6-dimethyl-1,4-phenylene oxide): A copolymer blend miscibility study

Joost de Wit; Gert Alberda van Ekenstein; Gerrit ten Brinke

doi:10.1016/j.polymer.2007.01.032

Interaction between poly(vinyl pyridine) and poly(2,6-dimethyl-1,4-phenylene oxide): A copolymer blend miscibility study

Joost de Wit, Gert Alberda van Ekenstein, Gerrit ten Brinke^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The phase behavior of blends of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) with random copolymers of styrene and 2-vinyl pyridine, Poly(S-co-2VP), as well as with random copolymers of styrene and 4-vinyl pyridine, Poly(S-co-4VP), has been investigated in order to estimate the values of the Flory-Huggins parameters chi(PPO),(2vp) and chi(PPO,4VP) between PPO and 2-vinyl pyridine, resp. 4-vinyl pyridine. Using previously estimated values for the Flory-Huggins parameters 0.09 <chi(S,2VP) <0.11 and 0.30 <chi(S,4VP) <0.35, together with the literature value of chi(S,PPO) = -0.043, the phase behavior observed as a function of the copolymer composition results in 0.11

Original language	English
Pages (from-to)	1606-1611
Number of pages	6
Journal	Polymer
Volume	48
Issue number	6
DOIs	https://doi.org/10.1016/j.polymer.2007.01.032
Publication status	Published - 8-Mar-2007

Keywords

random copolymer blend
interaction
phase behavior
SUPRAMOLECULAR POLYMERIC MATERIALS
BLOCK-COPOLYMER
PHASE-BEHAVIOR
DIBLOCK COPOLYMERS
MOLECULAR-WEIGHT
THIN-FILMS
FUNCTIONAL MATERIALS
ORDERED STRUCTURE
SOFT MATERIALS
POLYSTYRENE

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@article{02a7def1442245079ed2217a6347586b,

title = "Interaction between poly(vinyl pyridine) and poly(2,6-dimethyl-1,4-phenylene oxide): A copolymer blend miscibility study",

abstract = "The phase behavior of blends of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) with random copolymers of styrene and 2-vinyl pyridine, Poly(S-co-2VP), as well as with random copolymers of styrene and 4-vinyl pyridine, Poly(S-co-4VP), has been investigated in order to estimate the values of the Flory-Huggins parameters chi(PPO),(2vp) and chi(PPO,4VP) between PPO and 2-vinyl pyridine, resp. 4-vinyl pyridine. Using previously estimated values for the Flory-Huggins parameters 0.09 ",

keywords = "random copolymer blend, interaction, phase behavior, SUPRAMOLECULAR POLYMERIC MATERIALS, BLOCK-COPOLYMER, PHASE-BEHAVIOR, DIBLOCK COPOLYMERS, MOLECULAR-WEIGHT, THIN-FILMS, FUNCTIONAL MATERIALS, ORDERED STRUCTURE, SOFT MATERIALS, POLYSTYRENE",

author = "{de Wit}, Joost and {van Ekenstein}, {Gert Alberda} and {ten Brinke}, Gerrit",

year = "2007",

month = mar,

day = "8",

doi = "10.1016/j.polymer.2007.01.032",

language = "English",

volume = "48",

pages = "1606--1611",

journal = "Polymer",

issn = "0032-3861",

publisher = "ELSEVIER SCI LTD",

number = "6",

}

TY - JOUR

T1 - Interaction between poly(vinyl pyridine) and poly(2,6-dimethyl-1,4-phenylene oxide)

T2 - A copolymer blend miscibility study

AU - de Wit, Joost

AU - van Ekenstein, Gert Alberda

AU - ten Brinke, Gerrit

PY - 2007/3/8

Y1 - 2007/3/8

N2 - The phase behavior of blends of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) with random copolymers of styrene and 2-vinyl pyridine, Poly(S-co-2VP), as well as with random copolymers of styrene and 4-vinyl pyridine, Poly(S-co-4VP), has been investigated in order to estimate the values of the Flory-Huggins parameters chi(PPO),(2vp) and chi(PPO,4VP) between PPO and 2-vinyl pyridine, resp. 4-vinyl pyridine. Using previously estimated values for the Flory-Huggins parameters 0.09

AB - The phase behavior of blends of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) with random copolymers of styrene and 2-vinyl pyridine, Poly(S-co-2VP), as well as with random copolymers of styrene and 4-vinyl pyridine, Poly(S-co-4VP), has been investigated in order to estimate the values of the Flory-Huggins parameters chi(PPO),(2vp) and chi(PPO,4VP) between PPO and 2-vinyl pyridine, resp. 4-vinyl pyridine. Using previously estimated values for the Flory-Huggins parameters 0.09

KW - random copolymer blend

KW - interaction

KW - phase behavior

KW - SUPRAMOLECULAR POLYMERIC MATERIALS

KW - BLOCK-COPOLYMER

KW - PHASE-BEHAVIOR

KW - DIBLOCK COPOLYMERS

KW - MOLECULAR-WEIGHT

KW - THIN-FILMS

KW - FUNCTIONAL MATERIALS

KW - ORDERED STRUCTURE

KW - SOFT MATERIALS

KW - POLYSTYRENE

U2 - 10.1016/j.polymer.2007.01.032

DO - 10.1016/j.polymer.2007.01.032

M3 - Article

SN - 0032-3861

VL - 48

SP - 1606

EP - 1611

JO - Polymer

JF - Polymer

IS - 6

ER -

Interaction between poly(vinyl pyridine) and poly(2,6-dimethyl-1,4-phenylene oxide): A copolymer blend miscibility study

Abstract

Keywords

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