INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE: Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride

Rosa Fandos; Auke Meetsma; Jan H. Teuben

doi:10.1021/om00047a030

INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE: Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride

Rosa Fandos, Auke Meetsma, Jan H. Teuben

Stratingh Institute for Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Cp'TiCl3 (1; Cp' = eta-5-C5Me4(CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3 = CH2 (2) to yield Cp'TiCl2(CHPPh3) (3) plus the phosphonium salt (MePPh3)Cl. Complex 3 decomposes thermally to give [eta-5:eta-1-C5Me4(CH2)3O]TiCl2 (4), containing a Cp* -alkoxide-functionalized ligand. The molecular structure of 4 shows it as a pseudo three-legged piano-stool complex.

Original language	English
Pages (from-to)	59-60
Number of pages	2
Journal	Organometallics
Volume	10
Issue number	1
DOIs	https://doi.org/10.1021/om00047a030
Publication status	Published - Jan-1991

Keywords

CRYSTAL
YLIDES

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Fandos, R., Meetsma, A., & Teuben, J. H. (1991). INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE: Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride. Organometallics, 10(1), 59-60. https://doi.org/10.1021/om00047a030

Fandos, Rosa ; Meetsma, Auke ; Teuben, Jan H. / INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE : Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride. In: Organometallics. 1991 ; Vol. 10, No. 1. pp. 59-60.

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title = "INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE: Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride",

abstract = "Cp'TiCl3 (1; Cp' = eta-5-C5Me4(CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3 = CH2 (2) to yield Cp'TiCl2(CHPPh3) (3) plus the phosphonium salt (MePPh3)Cl. Complex 3 decomposes thermally to give [eta-5:eta-1-C5Me4(CH2)3O]TiCl2 (4), containing a Cp* -alkoxide-functionalized ligand. The molecular structure of 4 shows it as a pseudo three-legged piano-stool complex.",

keywords = "CRYSTAL, YLIDES",

author = "Rosa Fandos and Auke Meetsma and Teuben, {Jan H.}",

note = "Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute",

year = "1991",

month = jan,

doi = "10.1021/om00047a030",

language = "English",

volume = "10",

pages = "59--60",

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Fandos, R, Meetsma, A & Teuben, JH 1991, 'INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE: Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride', Organometallics, vol. 10, no. 1, pp. 59-60. https://doi.org/10.1021/om00047a030

INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE: Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride. / Fandos, Rosa; Meetsma, Auke; Teuben, Jan H.
In: Organometallics, Vol. 10, No. 1, 01.1991, p. 59-60.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE

T2 - Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride

AU - Fandos, Rosa

AU - Meetsma, Auke

AU - Teuben, Jan H.

N1 - Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute

PY - 1991/1

Y1 - 1991/1

N2 - Cp'TiCl3 (1; Cp' = eta-5-C5Me4(CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3 = CH2 (2) to yield Cp'TiCl2(CHPPh3) (3) plus the phosphonium salt (MePPh3)Cl. Complex 3 decomposes thermally to give [eta-5:eta-1-C5Me4(CH2)3O]TiCl2 (4), containing a Cp* -alkoxide-functionalized ligand. The molecular structure of 4 shows it as a pseudo three-legged piano-stool complex.

AB - Cp'TiCl3 (1; Cp' = eta-5-C5Me4(CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3 = CH2 (2) to yield Cp'TiCl2(CHPPh3) (3) plus the phosphonium salt (MePPh3)Cl. Complex 3 decomposes thermally to give [eta-5:eta-1-C5Me4(CH2)3O]TiCl2 (4), containing a Cp* -alkoxide-functionalized ligand. The molecular structure of 4 shows it as a pseudo three-legged piano-stool complex.

KW - CRYSTAL

KW - YLIDES

U2 - 10.1021/om00047a030

DO - 10.1021/om00047a030

M3 - Article

SN - 0276-7333

VL - 10

SP - 59

EP - 60

JO - Organometallics

JF - Organometallics

IS - 1

ER -

Fandos R, Meetsma A, Teuben JH. INTRAMOLECULAR C-X ACTIVATION AS A SYNTHETIC ROUTE TO BIDENTATE CYCLOPENTADIENYL-ALKOXIDE LIGANDS - PREPARATION AND MOLECULAR-STRUCTURE OF (3-(2,3,4,5-TETRAMETHYLCYCLOPENTADIENYL)PROPOXY)TITANIUM DICHLORIDE: Preparation and Molecular Structure of (3-(2,3,4,5-Tetramethylcyclopentadienyl)propoxy)titanium Dichloride. Organometallics. 1991 Jan;10(1):59-60. doi: 10.1021/om00047a030