Intrinsic Properties of Single Graphene Nanoribbons in Solution: Synthetic and Spectroscopic Studies

Yinjuan Huang; Fugui Xu; Lucia Ganzer; Franco Valduga de Almeida Camargo; Tetsuhiko Nagahara; Joan Teyssandier; Hans Van Gorp; K Basse; Lasse Arnt Straasø; Vaiva Nagyte; Cinzia Casiraghi; Michael Ryan Hansen; Steven De Feyter; Deyue Yan; Klaus Müllen; Xinliang Feng; Giulio Cerullo; Yiyong Mai

doi:10.1021/jacs.8b06028

Intrinsic Properties of Single Graphene Nanoribbons in Solution: Synthetic and Spectroscopic Studies

Yinjuan Huang, Fugui Xu, Lucia Ganzer, Franco Valduga de Almeida Camargo, Tetsuhiko Nagahara, Joan Teyssandier, Hans Van Gorp, K Basse, Lasse Arnt Straasø, Vaiva Nagyte, Cinzia Casiraghi, Michael Ryan Hansen, Steven De Feyter, Deyue Yan, Klaus Müllen, Xinliang Feng, Giulio Cerullo^*, Yiyong Mai^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

51 Citations (Scopus)

Abstract

We report a novel type of structurally defined graphene nanoribbons (GNRs) with uniform width of 1.7 nm and average length up to 58 nm. These GNRs are decorated with pending Diels–Alder cycloadducts of anthracenyl units and N-n-hexadecyl maleimide. The resultant bulky side groups on GNRs afford excellent dispersibility with concentrations of up to 5 mg mL–1 in many organic solvents such as tetrahydrofuran (THF), two orders of magnitude higher than the previously reported GNRs. Multiple spectroscopic studies confirm that dilute dispersions in THF (

Original language	English
Pages (from-to)	10416–10420
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	140
Issue number	33
DOIs	https://doi.org/10.1021/jacs.8b06028
Publication status	Published - 22-Aug-2018
Externally published	Yes

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Huang, Y., Xu, F., Ganzer, L., Camargo, F. V. D. A., Nagahara, T., Teyssandier, J., Van Gorp, H., Basse, K., Straasø, L. A., Nagyte, V., Casiraghi, C., Hansen, M. R., De Feyter, S., Yan, D., Müllen, K., Feng, X., Cerullo, G., & Mai, Y. (2018). Intrinsic Properties of Single Graphene Nanoribbons in Solution: Synthetic and Spectroscopic Studies. Journal of the American Chemical Society, 140(33), 10416–10420. https://doi.org/10.1021/jacs.8b06028

@article{d4805dc12abe48769b864b7d4e55670f,

title = "Intrinsic Properties of Single Graphene Nanoribbons in Solution: Synthetic and Spectroscopic Studies",

abstract = "We report a novel type of structurally defined graphene nanoribbons (GNRs) with uniform width of 1.7 nm and average length up to 58 nm. These GNRs are decorated with pending Diels–Alder cycloadducts of anthracenyl units and N-n-hexadecyl maleimide. The resultant bulky side groups on GNRs afford excellent dispersibility with concentrations of up to 5 mg mL–1 in many organic solvents such as tetrahydrofuran (THF), two orders of magnitude higher than the previously reported GNRs. Multiple spectroscopic studies confirm that dilute dispersions in THF (",

author = "Yinjuan Huang and Fugui Xu and Lucia Ganzer and Camargo, {Franco Valduga de Almeida} and Tetsuhiko Nagahara and Joan Teyssandier and {Van Gorp}, Hans and K Basse and Straas{\o}, {Lasse Arnt} and Vaiva Nagyte and Cinzia Casiraghi and Hansen, {Michael Ryan} and {De Feyter}, Steven and Deyue Yan and Klaus M{\"u}llen and Xinliang Feng and Giulio Cerullo and Yiyong Mai",

year = "2018",

month = aug,

day = "22",

doi = "10.1021/jacs.8b06028",

language = "English",

volume = "140",

pages = " 10416–10420",

journal = "Journal of the American Chemical Society",

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Huang, Y, Xu, F, Ganzer, L, Camargo, FVDA, Nagahara, T, Teyssandier, J, Van Gorp, H, Basse, K, Straasø, LA, Nagyte, V, Casiraghi, C, Hansen, MR, De Feyter, S, Yan, D, Müllen, K, Feng, X, Cerullo, G & Mai, Y 2018, 'Intrinsic Properties of Single Graphene Nanoribbons in Solution: Synthetic and Spectroscopic Studies', Journal of the American Chemical Society, vol. 140, no. 33, pp. 10416–10420. https://doi.org/10.1021/jacs.8b06028

TY - JOUR

T1 - Intrinsic Properties of Single Graphene Nanoribbons in Solution

T2 - Synthetic and Spectroscopic Studies

AU - Huang, Yinjuan

AU - Xu, Fugui

AU - Ganzer, Lucia

AU - Camargo, Franco Valduga de Almeida

AU - Nagahara, Tetsuhiko

AU - Teyssandier, Joan

AU - Van Gorp, Hans

AU - Basse, K

AU - Straasø, Lasse Arnt

AU - Nagyte, Vaiva

AU - Casiraghi, Cinzia

AU - Hansen, Michael Ryan

AU - De Feyter, Steven

AU - Yan, Deyue

AU - Müllen, Klaus

AU - Feng, Xinliang

AU - Cerullo, Giulio

AU - Mai, Yiyong

PY - 2018/8/22

Y1 - 2018/8/22

N2 - We report a novel type of structurally defined graphene nanoribbons (GNRs) with uniform width of 1.7 nm and average length up to 58 nm. These GNRs are decorated with pending Diels–Alder cycloadducts of anthracenyl units and N-n-hexadecyl maleimide. The resultant bulky side groups on GNRs afford excellent dispersibility with concentrations of up to 5 mg mL–1 in many organic solvents such as tetrahydrofuran (THF), two orders of magnitude higher than the previously reported GNRs. Multiple spectroscopic studies confirm that dilute dispersions in THF (

AB - We report a novel type of structurally defined graphene nanoribbons (GNRs) with uniform width of 1.7 nm and average length up to 58 nm. These GNRs are decorated with pending Diels–Alder cycloadducts of anthracenyl units and N-n-hexadecyl maleimide. The resultant bulky side groups on GNRs afford excellent dispersibility with concentrations of up to 5 mg mL–1 in many organic solvents such as tetrahydrofuran (THF), two orders of magnitude higher than the previously reported GNRs. Multiple spectroscopic studies confirm that dilute dispersions in THF (

UR - http://europepmc.org/abstract/med/30084630

U2 - 10.1021/jacs.8b06028

DO - 10.1021/jacs.8b06028

M3 - Article

C2 - 30084630

SN - 0002-7863

VL - 140

SP - 10416

EP - 10420

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 33

ER -

Intrinsic Properties of Single Graphene Nanoribbons in Solution: Synthetic and Spectroscopic Studies

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