Investigation of Ferri-alginate (Fe-Alg) as Environmentally Friendly Catalyst on the Formation of Solketal from Glycerol and Acetone

M. Mahreni; M. M.  Azimatun Nur

doi:10.1088/1757-899x/742/1/012010

Investigation of Ferri-alginate (Fe-Alg) as Environmentally Friendly Catalyst on the Formation of Solketal from Glycerol and Acetone

M. Mahreni, M. M. Azimatun Nur

Ocean Ecosystems

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

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Abstract

Alginate is a naturally occurring anionic carbohydrate polymer which could be coupled with metallic cationic molecules to form heterogeneous catalyst. However, the potency of the heterogeneous catalyst on the production of solketal was not explored. This research was proposed to investigate the potency of Ferri-Alginate (Fe-Alg) as a cheap and environmentally friendly catalyst in the solketal reaction. Fe-Alg was synthesized by reacting FeCl3 to sodium alginate with different concentrations (0.1 -0.5 M). Fe-Alg catalyst was characterized both on the physical and chemical activity. By using BET analysis, it was indicated that the addition of FeCl3 concentration increased the surface area of the catalyst. By using TGA/DSC analysis, it was found that Fe-Alg catalyst was stable up to 153°C. From GC/MS analysis, it was found that solketal was formed after the reaction of glycerol and acetone by using Fe-Alg as the catalyst.

Original language	English
Title of host publication	International Conference on Chemical Engineering UNPAR 2019
Publisher	IoP Publishing
Number of pages	8
Volume	742
DOIs	https://doi.org/10.1088/1757-899x/742/1/012010
Publication status	Published - 1-Mar-2020
Event	International Conference on Chemical Engineering UNPAR 2019 - Bandung, Indonesia Duration: 28-Nov-2019 → 29-Nov-2019

Publication series

Name	IOP Conference Series: Materials Science and Engineering
Publisher	IoP Publishing
Volume	742
ISSN (Print)	1757-8981

Conference

Conference	International Conference on Chemical Engineering UNPAR 2019
Country	Indonesia
City	Bandung
Period	28/11/2019 → 29/11/2019

Access to Document

10.1088/1757-899x/742/1/012010Licence: CC BY

Investigation of Ferri-alginate (Fe-Alg) as Environmentally Friendly Catalyst on the Formation of SolketalFinal publisher's version, 344 KBLicence: CC BY

Cite this

Mahreni, M., & Azimatun Nur, M. M. (2020). Investigation of Ferri-alginate (Fe-Alg) as Environmentally Friendly Catalyst on the Formation of Solketal from Glycerol and Acetone. In International Conference on Chemical Engineering UNPAR 2019 (Vol. 742). [012010] (IOP Conference Series: Materials Science and Engineering; Vol. 742). IoP Publishing. https://doi.org/10.1088/1757-899x/742/1/012010

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abstract = "Alginate is a naturally occurring anionic carbohydrate polymer which could be coupled with metallic cationic molecules to form heterogeneous catalyst. However, the potency of the heterogeneous catalyst on the production of solketal was not explored. This research was proposed to investigate the potency of Ferri-Alginate (Fe-Alg) as a cheap and environmentally friendly catalyst in the solketal reaction. Fe-Alg was synthesized by reacting FeCl3 to sodium alginate with different concentrations (0.1 -0.5 M). Fe-Alg catalyst was characterized both on the physical and chemical activity. By using BET analysis, it was indicated that the addition of FeCl3 concentration increased the surface area of the catalyst. By using TGA/DSC analysis, it was found that Fe-Alg catalyst was stable up to 153°C. From GC/MS analysis, it was found that solketal was formed after the reaction of glycerol and acetone by using Fe-Alg as the catalyst.",

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Mahreni, M & Azimatun Nur, MM 2020, Investigation of Ferri-alginate (Fe-Alg) as Environmentally Friendly Catalyst on the Formation of Solketal from Glycerol and Acetone. in International Conference on Chemical Engineering UNPAR 2019. vol. 742, 012010, IOP Conference Series: Materials Science and Engineering, vol. 742, IoP Publishing, International Conference on Chemical Engineering UNPAR 2019
, Bandung, Indonesia, 28/11/2019. https://doi.org/10.1088/1757-899x/742/1/012010

Investigation of Ferri-alginate (Fe-Alg) as Environmentally Friendly Catalyst on the Formation of Solketal from Glycerol and Acetone. / Mahreni, M.; Azimatun Nur, M. M. .

International Conference on Chemical Engineering UNPAR 2019. Vol. 742 IoP Publishing, 2020. 012010 (IOP Conference Series: Materials Science and Engineering; Vol. 742).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

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N2 - Alginate is a naturally occurring anionic carbohydrate polymer which could be coupled with metallic cationic molecules to form heterogeneous catalyst. However, the potency of the heterogeneous catalyst on the production of solketal was not explored. This research was proposed to investigate the potency of Ferri-Alginate (Fe-Alg) as a cheap and environmentally friendly catalyst in the solketal reaction. Fe-Alg was synthesized by reacting FeCl3 to sodium alginate with different concentrations (0.1 -0.5 M). Fe-Alg catalyst was characterized both on the physical and chemical activity. By using BET analysis, it was indicated that the addition of FeCl3 concentration increased the surface area of the catalyst. By using TGA/DSC analysis, it was found that Fe-Alg catalyst was stable up to 153°C. From GC/MS analysis, it was found that solketal was formed after the reaction of glycerol and acetone by using Fe-Alg as the catalyst.

AB - Alginate is a naturally occurring anionic carbohydrate polymer which could be coupled with metallic cationic molecules to form heterogeneous catalyst. However, the potency of the heterogeneous catalyst on the production of solketal was not explored. This research was proposed to investigate the potency of Ferri-Alginate (Fe-Alg) as a cheap and environmentally friendly catalyst in the solketal reaction. Fe-Alg was synthesized by reacting FeCl3 to sodium alginate with different concentrations (0.1 -0.5 M). Fe-Alg catalyst was characterized both on the physical and chemical activity. By using BET analysis, it was indicated that the addition of FeCl3 concentration increased the surface area of the catalyst. By using TGA/DSC analysis, it was found that Fe-Alg catalyst was stable up to 153°C. From GC/MS analysis, it was found that solketal was formed after the reaction of glycerol and acetone by using Fe-Alg as the catalyst.

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Mahreni M, Azimatun Nur MM. Investigation of Ferri-alginate (Fe-Alg) as Environmentally Friendly Catalyst on the Formation of Solketal from Glycerol and Acetone. In International Conference on Chemical Engineering UNPAR 2019. Vol. 742. IoP Publishing. 2020. 012010. (IOP Conference Series: Materials Science and Engineering). https://doi.org/10.1088/1757-899x/742/1/012010