LINEAR SOLVATION ENERGY RELATIONSHIPS FOR CHARACTERIZATION OF MLC SYSTEMS WITH SODIUM DODECYL SULPHATE MOBILE PHASES MODIFIED BY ALIPHATIC ALCOHOLS OR CARBOXYLIC ACIDS

Vadym V. Markov; Alexander P. Boichenko; Lidia P. Loginova

LINEAR SOLVATION ENERGY RELATIONSHIPS FOR CHARACTERIZATION OF MLC SYSTEMS WITH SODIUM DODECYL SULPHATE MOBILE PHASES MODIFIED BY ALIPHATIC ALCOHOLS OR CARBOXYLIC ACIDS

Vadym V. Markov^*, Alexander P. Boichenko, Lidia P. Loginova

^*Corresponding author for this work

Analytical Biochemistry

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The Linear Solvation Energy Relationships (LSER) have been successfully used for the modeling of partition and retention of the set of test compounds in different systems. The properties of micellar chromatographic systems with the mobile phases on the basis of sodium dodecylsulphate modified (ODS) by additives of aliphatic alcohols (1-butanol, 1-pentanol) or aliphatic carboxylic acids (butanoic, pentanoic) were characterized on the basis of comparison of calculated LSER coefficients. Principal component analysis (PCA) was used for the classification of studied systems.

Original language	English
Pages (from-to)	267-282
Number of pages	16
Journal	Studia universitatis babes-Bolyai chemia
Volume	57
Issue number	3
Publication status	Published - 2012

Keywords

Linear Solvation Energy Relationships (LSER)
partition
modeling
micelle bounding
Micellar Liquid Chromatography (MLC)
Principal Component Analysis (PCA)
MICELLAR LIQUID-CHROMATOGRAPHY
ELECTROKINETIC CAPILLARY CHROMATOGRAPHY
WATER PARTITION-COEFFICIENTS
SOLUTE ASSOCIATION CONSTANTS
GAS-PHASE
NAPHTHALENE DERIVATIVES
RETENTION RELATIONSHIPS
STATIONARY PHASES
PARAMETER MODEL
PREDICTION

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@article{bbd4cba30c1549f1aad05ed41567dc45,

title = "LINEAR SOLVATION ENERGY RELATIONSHIPS FOR CHARACTERIZATION OF MLC SYSTEMS WITH SODIUM DODECYL SULPHATE MOBILE PHASES MODIFIED BY ALIPHATIC ALCOHOLS OR CARBOXYLIC ACIDS",

abstract = "The Linear Solvation Energy Relationships (LSER) have been successfully used for the modeling of partition and retention of the set of test compounds in different systems. The properties of micellar chromatographic systems with the mobile phases on the basis of sodium dodecylsulphate modified (ODS) by additives of aliphatic alcohols (1-butanol, 1-pentanol) or aliphatic carboxylic acids (butanoic, pentanoic) were characterized on the basis of comparison of calculated LSER coefficients. Principal component analysis (PCA) was used for the classification of studied systems.",

keywords = "Linear Solvation Energy Relationships (LSER), partition, modeling, micelle bounding, Micellar Liquid Chromatography (MLC), Principal Component Analysis (PCA), MICELLAR LIQUID-CHROMATOGRAPHY, ELECTROKINETIC CAPILLARY CHROMATOGRAPHY, WATER PARTITION-COEFFICIENTS, SOLUTE ASSOCIATION CONSTANTS, GAS-PHASE, NAPHTHALENE DERIVATIVES, RETENTION RELATIONSHIPS, STATIONARY PHASES, PARAMETER MODEL, PREDICTION",

author = "Markov, {Vadym V.} and Boichenko, {Alexander P.} and Loginova, {Lidia P.}",

year = "2012",

language = "English",

volume = "57",

pages = "267--282",

journal = "Studia universitatis babes-Bolyai chemia",

issn = "1224-7154",

number = "3",

}

LINEAR SOLVATION ENERGY RELATIONSHIPS FOR CHARACTERIZATION OF MLC SYSTEMS WITH SODIUM DODECYL SULPHATE MOBILE PHASES MODIFIED BY ALIPHATIC ALCOHOLS OR CARBOXYLIC ACIDS. / Markov, Vadym V.; Boichenko, Alexander P.; Loginova, Lidia P.
In: Studia universitatis babes-Bolyai chemia, Vol. 57, No. 3, 2012, p. 267-282.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - LINEAR SOLVATION ENERGY RELATIONSHIPS FOR CHARACTERIZATION OF MLC SYSTEMS WITH SODIUM DODECYL SULPHATE MOBILE PHASES MODIFIED BY ALIPHATIC ALCOHOLS OR CARBOXYLIC ACIDS

AU - Markov, Vadym V.

AU - Boichenko, Alexander P.

AU - Loginova, Lidia P.

PY - 2012

Y1 - 2012

N2 - The Linear Solvation Energy Relationships (LSER) have been successfully used for the modeling of partition and retention of the set of test compounds in different systems. The properties of micellar chromatographic systems with the mobile phases on the basis of sodium dodecylsulphate modified (ODS) by additives of aliphatic alcohols (1-butanol, 1-pentanol) or aliphatic carboxylic acids (butanoic, pentanoic) were characterized on the basis of comparison of calculated LSER coefficients. Principal component analysis (PCA) was used for the classification of studied systems.

AB - The Linear Solvation Energy Relationships (LSER) have been successfully used for the modeling of partition and retention of the set of test compounds in different systems. The properties of micellar chromatographic systems with the mobile phases on the basis of sodium dodecylsulphate modified (ODS) by additives of aliphatic alcohols (1-butanol, 1-pentanol) or aliphatic carboxylic acids (butanoic, pentanoic) were characterized on the basis of comparison of calculated LSER coefficients. Principal component analysis (PCA) was used for the classification of studied systems.

KW - Linear Solvation Energy Relationships (LSER)

KW - partition

KW - modeling

KW - micelle bounding

KW - Micellar Liquid Chromatography (MLC)

KW - Principal Component Analysis (PCA)

KW - MICELLAR LIQUID-CHROMATOGRAPHY

KW - ELECTROKINETIC CAPILLARY CHROMATOGRAPHY

KW - WATER PARTITION-COEFFICIENTS

KW - SOLUTE ASSOCIATION CONSTANTS

KW - GAS-PHASE

KW - NAPHTHALENE DERIVATIVES

KW - RETENTION RELATIONSHIPS

KW - STATIONARY PHASES

KW - PARAMETER MODEL

KW - PREDICTION

M3 - Article

SN - 1224-7154

VL - 57

SP - 267

EP - 282

JO - Studia universitatis babes-Bolyai chemia

JF - Studia universitatis babes-Bolyai chemia

IS - 3

ER -

LINEAR SOLVATION ENERGY RELATIONSHIPS FOR CHARACTERIZATION OF MLC SYSTEMS WITH SODIUM DODECYL SULPHATE MOBILE PHASES MODIFIED BY ALIPHATIC ALCOHOLS OR CARBOXYLIC ACIDS

Abstract

Keywords

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