Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals

Artur A. Mannanov; Maxim S. Kazantsev; Anatoly D. Kuimov; Vladislav G. Konstantinov; Dmitry I. Dominskiy; Vasiliy A. Trukhanov; Daniil S. Anisimov; Nikita V. Gultikov; Vladimir V. Bruevich; Igor P. Koskin; Alina A. Sonina; Tatyana V. Rybalova; Inna K. Shundrina; Evgeny A. Mostovich; Dmitry Yu. Paraschuk; Maxim S. Pshenichnikov

doi:10.1039/c8tc04151b

Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals

Artur A. Mannanov, Maxim S. Kazantsev, Anatoly D. Kuimov, Vladislav G. Konstantinov, Dmitry I. Dominskiy, Vasiliy A. Trukhanov, Daniil S. Anisimov, Nikita V. Gultikov, Vladimir V. Bruevich, Igor P. Koskin, Alina A. Sonina, Tatyana V. Rybalova, Inna K. Shundrina, Evgeny A. Mostovich, Dmitry Yu. Paraschuk, Maxim S. Pshenichnikov

Optical Condensed Matter Physics

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Abstract

The design of light-emitting crystalline organic semiconductors for optoelectronic applications requires a thorough understanding of the singlet exciton transport process. In this study, we show that the singlet exciton diffusion length in a promising semiconductor crystal based on furan/phenylene co-oligomers is 24 nm. To achieve this, we employed the photoluminescence quenching technique using a specially synthesized quencher, which is a long furan/phenylene co-oligomer that was facilely implanted into the host crystal lattice. Extensive Monte-Carlo simulations, exciton-exciton annihilation experiments and numerical modelling fully supported our findings. We further demonstrated the high potential of the furan/phenylene co-oligomer crystals for light-emitting applications by fabricating solution-processed organic light emitting transistors.

Original language	English
Pages (from-to)	60-68
Number of pages	9
Journal	Journal of Materials Chemistry C
Volume	7
Issue number	1
DOIs	https://doi.org/10.1039/c8tc04151b
Publication status	Published - 7-Jan-2019

Keywords

FIELD-EFFECT TRANSISTORS
ANTHRACENE-CRYSTALS
CHARGE-TRANSPORT
SINGLE-CRYSTALS
MONTE-CARLO
DIFFUSION
ANNIHILATION
FURAN
FILMS
ELECTROLUMINESCENCE

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Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystalsFinal publisher's version, 5.99 MBLicence: Taverne

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CCDC 1851983: Experimental Crystal Structure Determination
Mannanov, A. (Contributor), Kazantsev, M. S. (Contributor), Kuimov, A. D. (Contributor), Konstantinov, V. G. (Contributor), Dominskiy, D. I. (Contributor), Trukhanov, V. A. (Contributor), Anisimov, D. S. (Contributor), Gultikov, N. V. (Contributor), Bruevich, V. V. (Contributor), Koskin, I. P. (Contributor), Sonina, A. A. (Contributor), Rybalova, T. V. (Contributor), Shundrina, I. K. (Contributor), Mostovich, E. A. (Contributor), Paraschuk, D. Y. (Contributor) & Pshenichnikov, M. S. (Contributor), The Cambridge Structural Database, 27-Jun-2018
DOI: 10.5517/ccdc.csd.cc2054dr
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Mannanov, A. A., Kazantsev, M. S., Kuimov, A. D., Konstantinov, V. G., Dominskiy, D. I., Trukhanov, V. A., Anisimov, D. S., Gultikov, N. V., Bruevich, V. V., Koskin, I. P., Sonina, A. A., Rybalova, T. V., Shundrina, I. K., Mostovich, E. A., Paraschuk, D. Y., & Pshenichnikov, M. S. (2019). Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals. Journal of Materials Chemistry C, 7(1), 60-68. https://doi.org/10.1039/c8tc04151b

@article{c8c6f5324e18421f97edf270d16f409a,

title = "Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals",

abstract = "The design of light-emitting crystalline organic semiconductors for optoelectronic applications requires a thorough understanding of the singlet exciton transport process. In this study, we show that the singlet exciton diffusion length in a promising semiconductor crystal based on furan/phenylene co-oligomers is 24 nm. To achieve this, we employed the photoluminescence quenching technique using a specially synthesized quencher, which is a long furan/phenylene co-oligomer that was facilely implanted into the host crystal lattice. Extensive Monte-Carlo simulations, exciton-exciton annihilation experiments and numerical modelling fully supported our findings. We further demonstrated the high potential of the furan/phenylene co-oligomer crystals for light-emitting applications by fabricating solution-processed organic light emitting transistors.",

keywords = "FIELD-EFFECT TRANSISTORS, ANTHRACENE-CRYSTALS, CHARGE-TRANSPORT, SINGLE-CRYSTALS, MONTE-CARLO, DIFFUSION, ANNIHILATION, FURAN, FILMS, ELECTROLUMINESCENCE",

author = "Mannanov, \{Artur A.\} and Kazantsev, \{Maxim S.\} and Kuimov, \{Anatoly D.\} and Konstantinov, \{Vladislav G.\} and Dominskiy, \{Dmitry I.\} and Trukhanov, \{Vasiliy A.\} and Anisimov, \{Daniil S.\} and Gultikov, \{Nikita V.\} and Bruevich, \{Vladimir V.\} and Koskin, \{Igor P.\} and Sonina, \{Alina A.\} and Rybalova, \{Tatyana V.\} and Shundrina, \{Inna K.\} and Mostovich, \{Evgeny A.\} and Paraschuk, \{Dmitry Yu.\} and Pshenichnikov, \{Maxim S.\}",

year = "2019",

month = jan,

day = "7",

doi = "10.1039/c8tc04151b",

language = "English",

volume = "7",

pages = "60--68",

journal = "Journal of Materials Chemistry C",

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Mannanov, AA, Kazantsev, MS, Kuimov, AD, Konstantinov, VG, Dominskiy, DI, Trukhanov, VA, Anisimov, DS, Gultikov, NV, Bruevich, VV, Koskin, IP, Sonina, AA, Rybalova, TV, Shundrina, IK, Mostovich, EA, Paraschuk, DY & Pshenichnikov, MS 2019, 'Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals', Journal of Materials Chemistry C, vol. 7, no. 1, pp. 60-68. https://doi.org/10.1039/c8tc04151b

TY - JOUR

T1 - Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals

AU - Mannanov, Artur A.

AU - Kazantsev, Maxim S.

AU - Kuimov, Anatoly D.

AU - Konstantinov, Vladislav G.

AU - Dominskiy, Dmitry I.

AU - Trukhanov, Vasiliy A.

AU - Anisimov, Daniil S.

AU - Gultikov, Nikita V.

AU - Bruevich, Vladimir V.

AU - Koskin, Igor P.

AU - Sonina, Alina A.

AU - Rybalova, Tatyana V.

AU - Shundrina, Inna K.

AU - Mostovich, Evgeny A.

AU - Paraschuk, Dmitry Yu.

AU - Pshenichnikov, Maxim S.

PY - 2019/1/7

Y1 - 2019/1/7

N2 - The design of light-emitting crystalline organic semiconductors for optoelectronic applications requires a thorough understanding of the singlet exciton transport process. In this study, we show that the singlet exciton diffusion length in a promising semiconductor crystal based on furan/phenylene co-oligomers is 24 nm. To achieve this, we employed the photoluminescence quenching technique using a specially synthesized quencher, which is a long furan/phenylene co-oligomer that was facilely implanted into the host crystal lattice. Extensive Monte-Carlo simulations, exciton-exciton annihilation experiments and numerical modelling fully supported our findings. We further demonstrated the high potential of the furan/phenylene co-oligomer crystals for light-emitting applications by fabricating solution-processed organic light emitting transistors.

AB - The design of light-emitting crystalline organic semiconductors for optoelectronic applications requires a thorough understanding of the singlet exciton transport process. In this study, we show that the singlet exciton diffusion length in a promising semiconductor crystal based on furan/phenylene co-oligomers is 24 nm. To achieve this, we employed the photoluminescence quenching technique using a specially synthesized quencher, which is a long furan/phenylene co-oligomer that was facilely implanted into the host crystal lattice. Extensive Monte-Carlo simulations, exciton-exciton annihilation experiments and numerical modelling fully supported our findings. We further demonstrated the high potential of the furan/phenylene co-oligomer crystals for light-emitting applications by fabricating solution-processed organic light emitting transistors.

KW - FIELD-EFFECT TRANSISTORS

KW - ANTHRACENE-CRYSTALS

KW - CHARGE-TRANSPORT

KW - SINGLE-CRYSTALS

KW - MONTE-CARLO

KW - DIFFUSION

KW - ANNIHILATION

KW - FURAN

KW - FILMS

KW - ELECTROLUMINESCENCE

U2 - 10.1039/c8tc04151b

DO - 10.1039/c8tc04151b

M3 - Article

SN - 2050-7526

VL - 7

SP - 60

EP - 68

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

IS - 1

ER -

Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals

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Datasets

CCDC 1851983: Experimental Crystal Structure Determination

Cite this