Mechanism of Building Block Exchange in Stacks of Self-Replicating Macrocycles

Elio Mattia; Asish Pal; Giulia Leonetti; Sijbren Otto

doi:10.1055/s-0036-1589709

Mechanism of Building Block Exchange in Stacks of Self-Replicating Macrocycles

Elio Mattia, Asish Pal, Giulia Leonetti, Sijbren Otto^*

^*Corresponding author for this work

Synthetic Organic Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Self-replicating molecules containing labile reversible covalent bonds are becoming increasingly topical. Yet their robustness to component exchange and the threat of loss of information has received very little attention. We show here that supramolecular interactions can efficiently protect self-replicating molecules from otherwise rapid component exchange.

Original language	English
Pages (from-to)	103-107
Number of pages	5
Journal	Synlett
Volume	28
Issue number	1
DOIs	https://doi.org/10.1055/s-0036-1589709
Publication status	Published - Jan-2017

Keywords

self-replication
self-assembly
exchange
supramolecular polymers
dynamic combinatorial chemistry
systems chemistry
SYSTEMS
SELECTION
EMERGENCE
LIBRARY
DRIVEN

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Mechanism of Building Block Exchange in Stacks of Self-Replicating MacrocyclesFinal publisher's version, 2.29 MBLicence: Taverne

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KW - self-replication

KW - self-assembly

KW - exchange

KW - supramolecular polymers

KW - dynamic combinatorial chemistry

KW - systems chemistry

KW - SYSTEMS

KW - SELECTION

KW - EMERGENCE

KW - LIBRARY

KW - DRIVEN

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Mechanism of Building Block Exchange in Stacks of Self-Replicating Macrocycles

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Keywords

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