Mechanisms in manganese catalysed oxidation of alkenes with H2O2

Pattama Saisaha; Johannes W. de Boer; Wesley R. Browne

doi:10.1039/c2cs35443h

Mechanisms in manganese catalysed oxidation of alkenes with H2O2

Pattama Saisaha
, Johannes W. de Boer
, Wesley R. Browne^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

159 Citations (Scopus)

1234 Downloads (Pure)

Abstract

The development of new catalytic systems for cis-dihydroxylation and epoxidation of alkenes, based on atom economic and environmentally friendly concepts, is a major contemporary challenge. In recent years, several systems based on manganese catalysts using H2O2 as the terminal oxidant have been developed. In this review, selected homogeneous manganese catalytic systems, including 'ligand free' and pyridyl amine ligand based systems, that have been applied to alkene oxidation will be discussed with a strong focus on the mechanistic studies that have been carried out.

Original language	English
Pages (from-to)	2059-2074
Number of pages	16
Journal	Chemical Society Reviews
Volume	42
Issue number	5
DOIs	https://doi.org/10.1039/c2cs35443h
Publication status	Published - 2013

Keywords

OLEFIN CIS-DIHYDROXYLATION
AQUEOUS HYDROGEN-PEROXIDE
NONHEME IRON CATALYSTS
ASYMMETRIC EPOXIDATION
DINUCLEAR MANGANESE
PERACETIC-ACID
METAL-OXO
ENANTIOSELECTIVE EPOXIDATION
TRIAZACYCLONONANE COMPLEXES
UNFUNCTIONALIZED OLEFINS

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@article{956bd99b41e74c5bad1a4e95c2c32137,

title = "Mechanisms in manganese catalysed oxidation of alkenes with H2O2",

abstract = "The development of new catalytic systems for cis-dihydroxylation and epoxidation of alkenes, based on atom economic and environmentally friendly concepts, is a major contemporary challenge. In recent years, several systems based on manganese catalysts using H2O2 as the terminal oxidant have been developed. In this review, selected homogeneous manganese catalytic systems, including 'ligand free' and pyridyl amine ligand based systems, that have been applied to alkene oxidation will be discussed with a strong focus on the mechanistic studies that have been carried out.",

keywords = "OLEFIN CIS-DIHYDROXYLATION, AQUEOUS HYDROGEN-PEROXIDE, NONHEME IRON CATALYSTS, ASYMMETRIC EPOXIDATION, DINUCLEAR MANGANESE, PERACETIC-ACID, METAL-OXO, ENANTIOSELECTIVE EPOXIDATION, TRIAZACYCLONONANE COMPLEXES, UNFUNCTIONALIZED OLEFINS",

author = "Pattama Saisaha and \{de Boer\}, \{Johannes W.\} and Browne, \{Wesley R.\}",

year = "2013",

doi = "10.1039/c2cs35443h",

language = "English",

volume = "42",

pages = "2059--2074",

journal = "Chemical Society Reviews",

issn = "0306-0012",

publisher = "ROYAL SOC CHEMISTRY",

number = "5",

}

TY - JOUR

T1 - Mechanisms in manganese catalysed oxidation of alkenes with H2O2

AU - Saisaha, Pattama

AU - de Boer, Johannes W.

AU - Browne, Wesley R.

PY - 2013

Y1 - 2013

N2 - The development of new catalytic systems for cis-dihydroxylation and epoxidation of alkenes, based on atom economic and environmentally friendly concepts, is a major contemporary challenge. In recent years, several systems based on manganese catalysts using H2O2 as the terminal oxidant have been developed. In this review, selected homogeneous manganese catalytic systems, including 'ligand free' and pyridyl amine ligand based systems, that have been applied to alkene oxidation will be discussed with a strong focus on the mechanistic studies that have been carried out.

AB - The development of new catalytic systems for cis-dihydroxylation and epoxidation of alkenes, based on atom economic and environmentally friendly concepts, is a major contemporary challenge. In recent years, several systems based on manganese catalysts using H2O2 as the terminal oxidant have been developed. In this review, selected homogeneous manganese catalytic systems, including 'ligand free' and pyridyl amine ligand based systems, that have been applied to alkene oxidation will be discussed with a strong focus on the mechanistic studies that have been carried out.

KW - OLEFIN CIS-DIHYDROXYLATION

KW - AQUEOUS HYDROGEN-PEROXIDE

KW - NONHEME IRON CATALYSTS

KW - ASYMMETRIC EPOXIDATION

KW - DINUCLEAR MANGANESE

KW - PERACETIC-ACID

KW - METAL-OXO

KW - ENANTIOSELECTIVE EPOXIDATION

KW - TRIAZACYCLONONANE COMPLEXES

KW - UNFUNCTIONALIZED OLEFINS

U2 - 10.1039/c2cs35443h

DO - 10.1039/c2cs35443h

M3 - Review article

SN - 0306-0012

VL - 42

SP - 2059

EP - 2074

JO - Chemical Society Reviews

JF - Chemical Society Reviews

IS - 5

ER -

Mechanisms in manganese catalysed oxidation of alkenes with H2O2

Abstract

Keywords

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