Modulation of the isomerization of iminothioindoxyl switches by supramolecular confinement

Daniel Doellerer; Ann-Kathrin Rückert; Sandra Doria; Michiel Hilbers; Nadja A Simeth; Wybren Jan Buma; Mariangela Di Donato; Ben L Feringa; Wiktor Szymanski; Stefano Crespi

doi:10.1039/d4cc02423k

Modulation of the isomerization of iminothioindoxyl switches by supramolecular confinement

Daniel Doellerer, Ann-Kathrin Rückert, Sandra Doria, Michiel Hilbers, Nadja A Simeth, Wybren Jan Buma, Mariangela Di Donato^*, Ben L Feringa^*, Wiktor Szymanski^*, Stefano Crespi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Here we present the formation of an iminothioindoxyl (ITI)⊂Cage complex that retains the photochemical properties of the photoswitch within a confined environment in water. At the same time, besides ultrafast switching inside the cage, the ITI photoswitch displays an intriguing bifurcation of the excited state isomerization pathway when encapsulated.

Original language	English
Article number	d4cc02423k
Pages (from-to)	9388-9391
Number of pages	4
Journal	Chemical communications (Cambridge, England)
Volume	60
Issue number	70
Early online date	12-Aug-2024
DOIs	https://doi.org/10.1039/d4cc02423k
Publication status	Published - 11-Sept-2024

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10.1039/d4cc02423kLicence: CC BY

Modulation of the isomerization of iminothioindoxyl switches by supramolecular confinementProof, 685 KBLicence: CC BY

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title = "Modulation of the isomerization of iminothioindoxyl switches by supramolecular confinement",

abstract = "Here we present the formation of an iminothioindoxyl (ITI)⊂Cage complex that retains the photochemical properties of the photoswitch within a confined environment in water. At the same time, besides ultrafast switching inside the cage, the ITI photoswitch displays an intriguing bifurcation of the excited state isomerization pathway when encapsulated.",

author = "Daniel Doellerer and Ann-Kathrin R{\"u}ckert and Sandra Doria and Michiel Hilbers and Simeth, {Nadja A} and Buma, {Wybren Jan} and {Di Donato}, Mariangela and Feringa, {Ben L} and Wiktor Szymanski and Stefano Crespi",

year = "2024",

month = sep,

day = "11",

doi = "10.1039/d4cc02423k",

language = "English",

volume = "60",

pages = "9388--9391",

journal = "Chemical communications (Cambridge, England)",

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T1 - Modulation of the isomerization of iminothioindoxyl switches by supramolecular confinement

AU - Doellerer, Daniel

AU - Rückert, Ann-Kathrin

AU - Doria, Sandra

AU - Hilbers, Michiel

AU - Simeth, Nadja A

AU - Buma, Wybren Jan

AU - Di Donato, Mariangela

AU - Feringa, Ben L

AU - Szymanski, Wiktor

AU - Crespi, Stefano

PY - 2024/9/11

Y1 - 2024/9/11

N2 - Here we present the formation of an iminothioindoxyl (ITI)⊂Cage complex that retains the photochemical properties of the photoswitch within a confined environment in water. At the same time, besides ultrafast switching inside the cage, the ITI photoswitch displays an intriguing bifurcation of the excited state isomerization pathway when encapsulated.

AB - Here we present the formation of an iminothioindoxyl (ITI)⊂Cage complex that retains the photochemical properties of the photoswitch within a confined environment in water. At the same time, besides ultrafast switching inside the cage, the ITI photoswitch displays an intriguing bifurcation of the excited state isomerization pathway when encapsulated.

U2 - 10.1039/d4cc02423k

DO - 10.1039/d4cc02423k

M3 - Article

C2 - 39132823

SN - 1359-7345

VL - 60

SP - 9388

EP - 9391

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

IS - 70

M1 - d4cc02423k

ER -

Modulation of the isomerization of iminothioindoxyl switches by supramolecular confinement

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