Mono-η-7-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

R GOMEZ; R DUCHATEAU; AN CHERNEGA; JH TEUBEN; FT EDELMANN; MLH GREEN

doi:10.1016/0022-328x(94)05237-6

Mono-η-7-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

R GOMEZ
, R DUCHATEAU
, AN CHERNEGA
, JH TEUBEN
, FT EDELMANN
, MLH GREEN^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

88 Citations (Scopus)

Abstract

The new compounds {M(eta-C(5)R(5))[eta-CPh(NSiMe(3))(2)]]Cl-2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(eta-C(5)R(5))([eta-CPh(NSiMe(3))(2)]Cl-2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(eta-C5H5)[eta-CPh(NSiMe(3))(2)]Cl-2} acts as a co-catalyst for the polymerisation of ethylene and propene.

Original language	English
Pages (from-to)	153-158
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	491
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328x(94)05237-6
Publication status	Published - 5-Apr-1995

Keywords

TITANIUM
ZIRCONIUM
HAFNIUM
ETA-CYCLOPENTADIERYL
BENZAMIDINATO
ZIEGLER-NATTA
MOLECULAR-STRUCTURE
CRYSTAL-STRUCTURE
COMPLEXES
POLYMERIZATION
CATALYSTS
ETHYLENE
REACTIVITY

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@article{2148b772c633434ebfd2a6e4164f2530,

title = "Mono-η-7-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium",

abstract = "The new compounds \{M(eta-C(5)R(5))[eta-CPh(NSiMe(3))(2)]]Cl-2\} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of \{M(eta-C(5)R(5))([eta-CPh(NSiMe(3))(2)]Cl-2\} (R = H, M = Zr or Hf) have been determined. The compound \{Zr(eta-C5H5)[eta-CPh(NSiMe(3))(2)]Cl-2\} acts as a co-catalyst for the polymerisation of ethylene and propene.",

keywords = "TITANIUM, ZIRCONIUM, HAFNIUM, ETA-CYCLOPENTADIERYL, BENZAMIDINATO, ZIEGLER-NATTA, MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURE, COMPLEXES, POLYMERIZATION, CATALYSTS, ETHYLENE, REACTIVITY",

author = "R GOMEZ and R DUCHATEAU and AN CHERNEGA and JH TEUBEN and FT EDELMANN and MLH GREEN",

note = "Journal PR 5 N890 ORGANOMETAL CHEM",

year = "1995",

month = apr,

day = "5",

doi = "10.1016/0022-328x(94)05237-6",

language = "English",

volume = "491",

pages = "153--158",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier Science",

number = "1-2",

}

TY - JOUR

T1 - Mono-η-7-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

AU - GOMEZ, R

AU - DUCHATEAU, R

AU - CHERNEGA, AN

AU - TEUBEN, JH

AU - EDELMANN, FT

AU - GREEN, MLH

N1 - Journal PR 5 N890 ORGANOMETAL CHEM

PY - 1995/4/5

Y1 - 1995/4/5

N2 - The new compounds {M(eta-C(5)R(5))[eta-CPh(NSiMe(3))(2)]]Cl-2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(eta-C(5)R(5))([eta-CPh(NSiMe(3))(2)]Cl-2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(eta-C5H5)[eta-CPh(NSiMe(3))(2)]Cl-2} acts as a co-catalyst for the polymerisation of ethylene and propene.

AB - The new compounds {M(eta-C(5)R(5))[eta-CPh(NSiMe(3))(2)]]Cl-2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(eta-C(5)R(5))([eta-CPh(NSiMe(3))(2)]Cl-2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(eta-C5H5)[eta-CPh(NSiMe(3))(2)]Cl-2} acts as a co-catalyst for the polymerisation of ethylene and propene.

KW - TITANIUM

KW - ZIRCONIUM

KW - HAFNIUM

KW - ETA-CYCLOPENTADIERYL

KW - BENZAMIDINATO

KW - ZIEGLER-NATTA

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

KW - POLYMERIZATION

KW - CATALYSTS

KW - ETHYLENE

KW - REACTIVITY

U2 - 10.1016/0022-328x(94)05237-6

DO - 10.1016/0022-328x(94)05237-6

M3 - Article

SN - 0022-328X

VL - 491

SP - 153

EP - 158

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Mono-η-7-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

Abstract

Keywords

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