Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

Rafael Gómez, Robbert Duchateau, Alexander N. Chernega, Jan H. Teuben, Frank T. Edelmann, Malcolm L.H. Green*

*Corresponding author for this work

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    Abstract

    The new compounds {M(η-C5R5)[η-CPh(NSiMe3)2]]Cl2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(η-C5R5)([η-CPh(NSiMe3)2]Cl2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(η-C5H5)[η-CPh(NSiMe3)2]Cl2} acts as a co-catalyst for the polymerisation of ethylene and propene.
    Original languageEnglish
    Pages (from-to)153-158
    Number of pages6
    JournalJournal of Organometallic Chemistry
    Volume491
    Publication statusPublished - 1995

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