Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

Rafael Gómez; Robbert Duchateau; Alexander N. Chernega; Jan H. Teuben; Frank T. Edelmann; Malcolm L.H. Green

Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

Rafael Gómez
, Robbert Duchateau
, Alexander N. Chernega
, Jan H. Teuben
, Frank T. Edelmann
, Malcolm L.H. Green^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The new compounds {M(η-C5R5)[η-CPh(NSiMe3)2]]Cl2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(η-C5R5)([η-CPh(NSiMe3)2]Cl2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(η-C5H5)[η-CPh(NSiMe3)2]Cl2} acts as a co-catalyst for the polymerisation of ethylene and propene.

Original language	English
Pages (from-to)	153-158
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	491
Publication status	Published - 1995

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Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium
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@article{820109a92f6048c3b45660242514506c,

title = "Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium",

abstract = "The new compounds \{M(η-C5R5)[η-CPh(NSiMe3)2]]Cl2\} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of \{M(η-C5R5)([η-CPh(NSiMe3)2]Cl2\} (R = H, M = Zr or Hf) have been determined. The compound \{Zr(η-C5H5)[η-CPh(NSiMe3)2]Cl2\} acts as a co-catalyst for the polymerisation of ethylene and propene.",

author = "Rafael G{\'o}mez and Robbert Duchateau and Chernega, \{Alexander N.\} and Teuben, \{Jan H.\} and Edelmann, \{Frank T.\} and Green, \{Malcolm L.H.\}",

note = "Relation: http://www.rug.nl/scheikunde/ date\_submitted:2005 Rights: University of Groningen. Stratingh Institute",

year = "1995",

language = "English",

volume = "491",

pages = "153--158",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier Science",

}

TY - JOUR

T1 - Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

AU - Gómez, Rafael

AU - Duchateau, Robbert

AU - Chernega, Alexander N.

AU - Teuben, Jan H.

AU - Edelmann, Frank T.

AU - Green, Malcolm L.H.

N1 - Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute

PY - 1995

Y1 - 1995

N2 - The new compounds {M(η-C5R5)[η-CPh(NSiMe3)2]]Cl2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(η-C5R5)([η-CPh(NSiMe3)2]Cl2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(η-C5H5)[η-CPh(NSiMe3)2]Cl2} acts as a co-catalyst for the polymerisation of ethylene and propene.

AB - The new compounds {M(η-C5R5)[η-CPh(NSiMe3)2]]Cl2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(η-C5R5)([η-CPh(NSiMe3)2]Cl2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(η-C5H5)[η-CPh(NSiMe3)2]Cl2} acts as a co-catalyst for the polymerisation of ethylene and propene.

M3 - Article

SN - 0022-328X

VL - 491

SP - 153

EP - 158

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Mono-η-cyclopentadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium

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