MONOCYCLOPENTADIENYL YTTRIUM CHEMISTRY - INCORPORATION OF ALKOXIDES AS SUPPORTING LIGANDS AND SYNTHESIS OF [Y(C5ME5)(OC6H3(BU-TERT)2)(MU-H)]2

CJ SCHAVERIEN; JHG FRIJNS; HJ HEERES; [No Value] VANDENHENDE; JH TEUBEN; AL SPEK

MONOCYCLOPENTADIENYL YTTRIUM CHEMISTRY - INCORPORATION OF ALKOXIDES AS SUPPORTING LIGANDS AND SYNTHESIS OF [Y(C5ME5)(OC6H3(BU-TERT)2)(MU-H)]2

CJ SCHAVERIEN^*, JHG FRIJNS, HJ HEERES, [No Value] VANDENHENDE, JH TEUBEN, AL SPEK

^*Corresponding author for this work

Stratingh Institute for Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Reaction of the crystallographically characterised [Y(C5Me5)(OC6H3Bu(t)2)2] 2 with LiCH(SiMe3)2 affords the mixed alkyl-alkoxide species [Y(C5Me5){CH(SiMe3)2}(OC6H3Bu(t)2)] 3 which, on subsequent hydrogenation, gives the hydride bridged dimer [{Y(C5Me5)(OC6H3Bu(t)2)(mu-H)}2] 4; Y-89 NMR spectra of these, and related complexes, allows C5Me5, OC6H3Bu(t)2 and CH(SiMe3)2 group contributions to be determined.

Original language	English
Pages (from-to)	642-644
Number of pages	3
Journal	Journal of the Chemical Society-Chemical Communications
Issue number	9
Publication status	Published - 1-May-1991

Keywords

RAY CRYSTAL-STRUCTURE
HIGHLY REACTIVE ORGANOLANTHANIDES
ORGANOYTTRIUM HYDRIDE CHEMISTRY
PERMETHYLYTTROCENE DERIVATIVES
COMPLEXES
BIS(PENTAMETHYLCYCLOPENTADIENYL)
METAL
HYDROCARBYLS
ARYLOXIDES
BONDS

Handle.net

Persistent link

Cite this

@article{e553774b091c48d388d87b16890eb4ed,

title = "MONOCYCLOPENTADIENYL YTTRIUM CHEMISTRY - INCORPORATION OF ALKOXIDES AS SUPPORTING LIGANDS AND SYNTHESIS OF [Y(C5ME5)(OC6H3(BU-TERT)2)(MU-H)]2",

abstract = "Reaction of the crystallographically characterised [Y(C5Me5)(OC6H3Bu(t)2)2] 2 with LiCH(SiMe3)2 affords the mixed alkyl-alkoxide species [Y(C5Me5){CH(SiMe3)2}(OC6H3Bu(t)2)] 3 which, on subsequent hydrogenation, gives the hydride bridged dimer [{Y(C5Me5)(OC6H3Bu(t)2)(mu-H)}2] 4; Y-89 NMR spectra of these, and related complexes, allows C5Me5, OC6H3Bu(t)2 and CH(SiMe3)2 group contributions to be determined.",

keywords = "RAY CRYSTAL-STRUCTURE, HIGHLY REACTIVE ORGANOLANTHANIDES, ORGANOYTTRIUM HYDRIDE CHEMISTRY, PERMETHYLYTTROCENE DERIVATIVES, COMPLEXES, BIS(PENTAMETHYLCYCLOPENTADIENYL), METAL, HYDROCARBYLS, ARYLOXIDES, BONDS",

author = "CJ SCHAVERIEN and JHG FRIJNS and HJ HEERES and VANDENHENDE, {[No Value]} and JH TEUBEN and AL SPEK",

year = "1991",

month = may,

day = "1",

language = "English",

pages = "642--644",

journal = "Journal of the Chemical Society-Chemical Communications",

issn = "0022-4936",

publisher = "ROYAL SOC CHEMISTRY",

number = "9",

}

TY - JOUR

T1 - MONOCYCLOPENTADIENYL YTTRIUM CHEMISTRY - INCORPORATION OF ALKOXIDES AS SUPPORTING LIGANDS AND SYNTHESIS OF [Y(C5ME5)(OC6H3(BU-TERT)2)(MU-H)]2

AU - SCHAVERIEN, CJ

AU - FRIJNS, JHG

AU - HEERES, HJ

AU - VANDENHENDE, [No Value]

AU - TEUBEN, JH

AU - SPEK, AL

PY - 1991/5/1

Y1 - 1991/5/1

N2 - Reaction of the crystallographically characterised [Y(C5Me5)(OC6H3Bu(t)2)2] 2 with LiCH(SiMe3)2 affords the mixed alkyl-alkoxide species [Y(C5Me5){CH(SiMe3)2}(OC6H3Bu(t)2)] 3 which, on subsequent hydrogenation, gives the hydride bridged dimer [{Y(C5Me5)(OC6H3Bu(t)2)(mu-H)}2] 4; Y-89 NMR spectra of these, and related complexes, allows C5Me5, OC6H3Bu(t)2 and CH(SiMe3)2 group contributions to be determined.

AB - Reaction of the crystallographically characterised [Y(C5Me5)(OC6H3Bu(t)2)2] 2 with LiCH(SiMe3)2 affords the mixed alkyl-alkoxide species [Y(C5Me5){CH(SiMe3)2}(OC6H3Bu(t)2)] 3 which, on subsequent hydrogenation, gives the hydride bridged dimer [{Y(C5Me5)(OC6H3Bu(t)2)(mu-H)}2] 4; Y-89 NMR spectra of these, and related complexes, allows C5Me5, OC6H3Bu(t)2 and CH(SiMe3)2 group contributions to be determined.

KW - RAY CRYSTAL-STRUCTURE

KW - HIGHLY REACTIVE ORGANOLANTHANIDES

KW - ORGANOYTTRIUM HYDRIDE CHEMISTRY

KW - PERMETHYLYTTROCENE DERIVATIVES

KW - COMPLEXES

KW - BIS(PENTAMETHYLCYCLOPENTADIENYL)

KW - METAL

KW - HYDROCARBYLS

KW - ARYLOXIDES

KW - BONDS

M3 - Article

SN - 0022-4936

SP - 642

EP - 644

JO - Journal of the Chemical Society-Chemical Communications

JF - Journal of the Chemical Society-Chemical Communications

IS - 9

ER -

MONOCYCLOPENTADIENYL YTTRIUM CHEMISTRY - INCORPORATION OF ALKOXIDES AS SUPPORTING LIGANDS AND SYNTHESIS OF [Y(C5ME5)(OC6H3(BU-TERT)2)(MU-H)]2

Abstract

Keywords

Handle.net

Fingerprint

Cite this