Monodisperse Colloidal Gallium Nanoparticles: Synthesis, Low Temperature Crystallization, Surface Plasmon Resonance and Li-Ion Storage

Maksym Yarema, Michael Woerle, Marta D. Rossell, Rolf Erni, Riccarda Caputo, Loredana Protesescu, Kostiantyn V. Kravchyk, Dmitry N. Dirin, Karla Lienau, Fabian von Rohr, Andreas Schilling, Maarten Nachtegaal, Maksym V. Kovalenko*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

We report a facile colloidal synthesis of gallium (Ga) nanopartides with the mean size tunable in the range of 12-46 nm and with excellent size distribution as small as 7-8%. When stored under ambient conditions, Ga nanoparticles remain stable for months due to the formation of native and passivating Ga-oxide layer (2-3 nm). The mechanism of Ga nanoparticles formation is elucidated using nuclear magnetic resonance spectroscopy and with molecular dynamics simulations. Size-dependent crystallization and melting of Ga nanoparticles in the temperature range of 98-298 K are studied with X-ray powder diffraction, specific heat measurements, transmission electron microscopy, and X-ray absorption spectroscopy. The results point to delta (delta)-Ga polymorph as a single low-temperature phase, while phase transition is characterized by the large hysteresis and by the large undercooling of crystallization and melting points down to 140-145 and 240-250 K, respectively. We have observed size-tunable plasmon resonance in the ultraviolet and visible spectral regions. We also report stable operation of Ga nanoparticles as anode material for Li-ion batteries with storage capacities of 600 mAh g(-1), 50% higher than those achieved for bulk Ga under identical testing conditions.

Original languageEnglish
Pages (from-to)12422-12430
Number of pages9
JournalJournal of the American Chemical Society
Volume136
Issue number35
DOIs
Publication statusPublished - 3-Sep-2014
Externally publishedYes

Keywords

  • LIQUID-SOLID GROWTH
  • PHASE-TRANSITIONS
  • BATTERY ANODES
  • SILICON NANOWIRES
  • CRYSTAL-STRUCTURE
  • PHOTONIC SWITCH
  • POROUS-GLASS
  • X-RAY
  • GA
  • NANOCRYSTALS

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