Nanostructured polystyrene-block-poly(4-vinyl pyridine)(pentadecylphenol) thin films as templates for polypyrrole synthesis

Wendy van Zoelen; Sasa Bondzic; Tatiana Fernández Landaluce; Johan Brondijk; Katja Loos; Arend-Jan Schouten; Petra Rudolf; Gerrit ten Brinke

doi:10.1016/j.polymer.2009.06.012

Nanostructured polystyrene-block-poly(4-vinyl pyridine)(pentadecylphenol) thin films as templates for polypyrrole synthesis

Wendy van Zoelen, Sasa Bondzic, Tatiana Fernández Landaluce, Johan Brondijk, Katja Loos, Arend-Jan Schouten, Petra Rudolf, Gerrit ten Brinke

Zernike Institute for Advanced Materials

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Abstract

Polypyrrole has been chemically synthesized on thin film nanostructures obtained from comb-shaped supramolecules of polystyrene-block-poly(4-vinyl pyridine) (PS-b-P4VP) hydrogen bonded with pentadecylphenol (PDP). PDP was washed from thin films of cylindrical and lamellar self-assembled combcopolymer systems, which resulted in removal of the upper layers of microdomains, leaving single cylindrical and lamellar layers covering a substrate, with P4VP segregated at the bottom as well as at the free air interface. This P4VP was complexed with Cu(2+) ions, after which chemical oxidation polymerization of pyrrole resulted in a thin polypyrrole layer covering the nanostructured block copolymer. The use of a catalytic amount of bipyrrole greatly improved the quality of the obtained product. The conductivity was measured to be similar to 0.7 S cm(-1). (C) 2009 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	3617-3625
Number of pages	9
Journal	Polymer
Volume	50
Issue number	15
DOIs	https://doi.org/10.1016/j.polymer.2009.06.012
Publication status	Published - 17-Jul-2009

Keywords

Block copolymers
Comb-shaped supramolecules
Polypyrrole
CONDUCTING POLYMERS
CHEMICAL SYNTHESIS
AQUEOUS-SOLUTION
POLYMERIZATION
OVEROXIDATION
COMPLEXES
PYRROLE

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@article{ecfd95b101744359b20e504170e13138,

title = "Nanostructured polystyrene-block-poly(4-vinyl pyridine)(pentadecylphenol) thin films as templates for polypyrrole synthesis",

abstract = "Polypyrrole has been chemically synthesized on thin film nanostructures obtained from comb-shaped supramolecules of polystyrene-block-poly(4-vinyl pyridine) (PS-b-P4VP) hydrogen bonded with pentadecylphenol (PDP). PDP was washed from thin films of cylindrical and lamellar self-assembled combcopolymer systems, which resulted in removal of the upper layers of microdomains, leaving single cylindrical and lamellar layers covering a substrate, with P4VP segregated at the bottom as well as at the free air interface. This P4VP was complexed with Cu(2+) ions, after which chemical oxidation polymerization of pyrrole resulted in a thin polypyrrole layer covering the nanostructured block copolymer. The use of a catalytic amount of bipyrrole greatly improved the quality of the obtained product. The conductivity was measured to be similar to 0.7 S cm(-1). (C) 2009 Elsevier Ltd. All rights reserved.",

keywords = "Block copolymers, Comb-shaped supramolecules, Polypyrrole, CONDUCTING POLYMERS, CHEMICAL SYNTHESIS, AQUEOUS-SOLUTION, POLYMERIZATION, OVEROXIDATION, COMPLEXES, PYRROLE",

author = "Zoelen, {Wendy van} and Sasa Bondzic and {Fern{\'a}ndez Landaluce}, Tatiana and Johan Brondijk and Katja Loos and Arend-Jan Schouten and Petra Rudolf and Brinke, {Gerrit ten}",

note = "Relation: http://www.rug.nl/zernike/ Rights: University of Groningen, Zernike Institute for Advanced Materials",

year = "2009",

month = jul,

day = "17",

doi = "10.1016/j.polymer.2009.06.012",

language = "English",

volume = "50",

pages = "3617--3625",

journal = "Polymer",

issn = "0032-3861",

publisher = "ELSEVIER SCI LTD",

number = "15",

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TY - JOUR

T1 - Nanostructured polystyrene-block-poly(4-vinyl pyridine)(pentadecylphenol) thin films as templates for polypyrrole synthesis

AU - Zoelen, Wendy van

AU - Bondzic, Sasa

AU - Fernández Landaluce, Tatiana

AU - Brondijk, Johan

AU - Loos, Katja

AU - Schouten, Arend-Jan

AU - Rudolf, Petra

AU - Brinke, Gerrit ten

N1 - Relation: http://www.rug.nl/zernike/ Rights: University of Groningen, Zernike Institute for Advanced Materials

PY - 2009/7/17

Y1 - 2009/7/17

N2 - Polypyrrole has been chemically synthesized on thin film nanostructures obtained from comb-shaped supramolecules of polystyrene-block-poly(4-vinyl pyridine) (PS-b-P4VP) hydrogen bonded with pentadecylphenol (PDP). PDP was washed from thin films of cylindrical and lamellar self-assembled combcopolymer systems, which resulted in removal of the upper layers of microdomains, leaving single cylindrical and lamellar layers covering a substrate, with P4VP segregated at the bottom as well as at the free air interface. This P4VP was complexed with Cu(2+) ions, after which chemical oxidation polymerization of pyrrole resulted in a thin polypyrrole layer covering the nanostructured block copolymer. The use of a catalytic amount of bipyrrole greatly improved the quality of the obtained product. The conductivity was measured to be similar to 0.7 S cm(-1). (C) 2009 Elsevier Ltd. All rights reserved.

AB - Polypyrrole has been chemically synthesized on thin film nanostructures obtained from comb-shaped supramolecules of polystyrene-block-poly(4-vinyl pyridine) (PS-b-P4VP) hydrogen bonded with pentadecylphenol (PDP). PDP was washed from thin films of cylindrical and lamellar self-assembled combcopolymer systems, which resulted in removal of the upper layers of microdomains, leaving single cylindrical and lamellar layers covering a substrate, with P4VP segregated at the bottom as well as at the free air interface. This P4VP was complexed with Cu(2+) ions, after which chemical oxidation polymerization of pyrrole resulted in a thin polypyrrole layer covering the nanostructured block copolymer. The use of a catalytic amount of bipyrrole greatly improved the quality of the obtained product. The conductivity was measured to be similar to 0.7 S cm(-1). (C) 2009 Elsevier Ltd. All rights reserved.

KW - Block copolymers

KW - Comb-shaped supramolecules

KW - Polypyrrole

KW - CONDUCTING POLYMERS

KW - CHEMICAL SYNTHESIS

KW - AQUEOUS-SOLUTION

KW - POLYMERIZATION

KW - OVEROXIDATION

KW - COMPLEXES

KW - PYRROLE

U2 - 10.1016/j.polymer.2009.06.012

DO - 10.1016/j.polymer.2009.06.012

M3 - Article

SN - 0032-3861

VL - 50

SP - 3617

EP - 3625

JO - Polymer

JF - Polymer

IS - 15

ER -

Nanostructured polystyrene-block-poly(4-vinyl pyridine)(pentadecylphenol) thin films as templates for polypyrrole synthesis

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Keywords

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