Non-Resonant Light Scattering in Pyrazine and Its Quantum Yield

Harry Th. Jonkman; Karel E. Drabe; Jan Kommandeur

doi:10.1016/0009-2614(85)80184-6

Non-Resonant Light Scattering in Pyrazine and Its Quantum Yield

Harry Th. Jonkman, Karel E. Drabe, Jan Kommandeur

Zernike Institute for Advanced Materials

Research output: Contribution to journal › Article › Academic › peer-review

18 Citations (Scopus)

Abstract

The ratio of the fast to the slow component in the decay of the 1B3u state of pyrazine is shown to vary strongly across the rotational manifold. In P(1) the fast component is absent, between the transitions it is dominant. Therefore, the excitation spectrum depends on the time the fluorescence is registered. The effects are due to non-resonant light scattering (NRLS), which because of its high quantum yield, shows up as unexpectedly strong. NRLS contributes to the fast component.

Original language	English
Pages (from-to)	357-362
Number of pages	6
Journal	Chemical Physics Letters
Volume	116
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(85)80184-6
Publication status	Published - 1985

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abstract = "The ratio of the fast to the slow component in the decay of the 1B3u state of pyrazine is shown to vary strongly across the rotational manifold. In P(1) the fast component is absent, between the transitions it is dominant. Therefore, the excitation spectrum depends on the time the fluorescence is registered. The effects are due to non-resonant light scattering (NRLS), which because of its high quantum yield, shows up as unexpectedly strong. NRLS contributes to the fast component.",

author = "Jonkman, {Harry Th.} and Drabe, {Karel E.} and Jan Kommandeur",

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AU - Drabe, Karel E.

AU - Kommandeur, Jan

N1 - Relation: http://www.rug.nl/scheikunde/ date_submitted:2006 Rights: University of Groningen. Materials Science Centre

PY - 1985

Y1 - 1985

N2 - The ratio of the fast to the slow component in the decay of the 1B3u state of pyrazine is shown to vary strongly across the rotational manifold. In P(1) the fast component is absent, between the transitions it is dominant. Therefore, the excitation spectrum depends on the time the fluorescence is registered. The effects are due to non-resonant light scattering (NRLS), which because of its high quantum yield, shows up as unexpectedly strong. NRLS contributes to the fast component.

AB - The ratio of the fast to the slow component in the decay of the 1B3u state of pyrazine is shown to vary strongly across the rotational manifold. In P(1) the fast component is absent, between the transitions it is dominant. Therefore, the excitation spectrum depends on the time the fluorescence is registered. The effects are due to non-resonant light scattering (NRLS), which because of its high quantum yield, shows up as unexpectedly strong. NRLS contributes to the fast component.

U2 - 10.1016/0009-2614(85)80184-6

DO - 10.1016/0009-2614(85)80184-6

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VL - 116

SP - 357

EP - 362

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5

ER -

Non-Resonant Light Scattering in Pyrazine and Its Quantum Yield

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