Novel uric acid-based nano organocatalyst with phosphorous acid tags: Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation

Sima Kalhor; Mahmoud Zarei; Hassan Sepehrmansourie; Mohammad Ali Zolfigol; Hu Shi; Jinping Wang; Jalal Arjomandi; Masoumeh Hasani; Romana Schirhagl

doi:10.1016/j.mcat.2021.111549

Novel uric acid-based nano organocatalyst with phosphorous acid tags: Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation

Sima Kalhor^*, Mahmoud Zarei, Hassan Sepehrmansourie, Mohammad Ali Zolfigol, Hu Shi, Jinping Wang, Jalal Arjomandi, Masoumeh Hasani, Romana Schirhagl

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

In this study, we have designed, synthesized and full characterized a novel biological based acidic nano organocatalyst via condensations reaction of uric acid and phosphorous acid. The obtained compound was named theacrine tetrakis(phosphonic acid) (TTPA) and prepared under refluxing ethanol. This new nano organocatalyst was applied as an efficient and recyclable catalyst for the preparation of novel pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation with good to excellent yields.

Original language	English
Article number	111549
Number of pages	16
Journal	Molecular catalysis
Volume	507
Early online date	20-Apr-2021
DOIs	https://doi.org/10.1016/j.mcat.2021.111549
Publication status	Published - May-2021

Keywords

(2-Methyl-1H-indol-3-yl)-pyrazolo[3,4-b]pyridine
Phosphorous acid
theacrine tetrakis (phosphonic acid) (TTPA)
Uric acid
Vinyligous anomeric based oxidation
IONIC LIQUID
EFFICIENT CATALYST
STRUCTURAL-CHARACTERIZATION
MOLTEN-SALT
GREEN
DERIVATIVES
GLYCOLURIL
COMPLEXES
DESIGN

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10.1016/j.mcat.2021.111549

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Kalhor, S., Zarei, M., Sepehrmansourie, H., Zolfigol, M. A., Shi, H., Wang, J., Arjomandi, J., Hasani, M., & Schirhagl, R. (2021). Novel uric acid-based nano organocatalyst with phosphorous acid tags: Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation. Molecular catalysis, 507, [111549]. https://doi.org/10.1016/j.mcat.2021.111549

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title = "Novel uric acid-based nano organocatalyst with phosphorous acid tags: Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation",

abstract = "In this study, we have designed, synthesized and full characterized a novel biological based acidic nano organocatalyst via condensations reaction of uric acid and phosphorous acid. The obtained compound was named theacrine tetrakis(phosphonic acid) (TTPA) and prepared under refluxing ethanol. This new nano organocatalyst was applied as an efficient and recyclable catalyst for the preparation of novel pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation with good to excellent yields.",

keywords = "(2-Methyl-1H-indol-3-yl)-pyrazolo[3,4-b]pyridine, Phosphorous acid, theacrine tetrakis (phosphonic acid) (TTPA), Uric acid, Vinyligous anomeric based oxidation, IONIC LIQUID, EFFICIENT CATALYST, STRUCTURAL-CHARACTERIZATION, MOLTEN-SALT, GREEN, DERIVATIVES, GLYCOLURIL, COMPLEXES, DESIGN",

author = "Sima Kalhor and Mahmoud Zarei and Hassan Sepehrmansourie and Zolfigol, {Mohammad Ali} and Hu Shi and Jinping Wang and Jalal Arjomandi and Masoumeh Hasani and Romana Schirhagl",

year = "2021",

month = may,

doi = "10.1016/j.mcat.2021.111549",

language = "English",

volume = "507",

journal = "Molecular catalysis",

issn = "2468-8231",

publisher = "Elsevier",

}

Kalhor, S, Zarei, M, Sepehrmansourie, H, Zolfigol, MA, Shi, H, Wang, J, Arjomandi, J, Hasani, M & Schirhagl, R 2021, 'Novel uric acid-based nano organocatalyst with phosphorous acid tags: Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation', Molecular catalysis, vol. 507, 111549. https://doi.org/10.1016/j.mcat.2021.111549

Novel uric acid-based nano organocatalyst with phosphorous acid tags : Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation. / Kalhor, Sima; Zarei, Mahmoud; Sepehrmansourie, Hassan et al.

In: Molecular catalysis, Vol. 507, 111549, 05.2021.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Novel uric acid-based nano organocatalyst with phosphorous acid tags

T2 - Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation

AU - Kalhor, Sima

AU - Zarei, Mahmoud

AU - Sepehrmansourie, Hassan

AU - Zolfigol, Mohammad Ali

AU - Shi, Hu

AU - Wang, Jinping

AU - Arjomandi, Jalal

AU - Hasani, Masoumeh

AU - Schirhagl, Romana

PY - 2021/5

Y1 - 2021/5

N2 - In this study, we have designed, synthesized and full characterized a novel biological based acidic nano organocatalyst via condensations reaction of uric acid and phosphorous acid. The obtained compound was named theacrine tetrakis(phosphonic acid) (TTPA) and prepared under refluxing ethanol. This new nano organocatalyst was applied as an efficient and recyclable catalyst for the preparation of novel pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation with good to excellent yields.

AB - In this study, we have designed, synthesized and full characterized a novel biological based acidic nano organocatalyst via condensations reaction of uric acid and phosphorous acid. The obtained compound was named theacrine tetrakis(phosphonic acid) (TTPA) and prepared under refluxing ethanol. This new nano organocatalyst was applied as an efficient and recyclable catalyst for the preparation of novel pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation with good to excellent yields.

KW - (2-Methyl-1H-indol-3-yl)-pyrazolo[3,4-b]pyridine

KW - Phosphorous acid

KW - theacrine tetrakis (phosphonic acid) (TTPA)

KW - Uric acid

KW - Vinyligous anomeric based oxidation

KW - IONIC LIQUID

KW - EFFICIENT CATALYST

KW - STRUCTURAL-CHARACTERIZATION

KW - MOLTEN-SALT

KW - GREEN

KW - DERIVATIVES

KW - GLYCOLURIL

KW - COMPLEXES

KW - DESIGN

U2 - 10.1016/j.mcat.2021.111549

DO - 10.1016/j.mcat.2021.111549

M3 - Article

SN - 2468-8231

VL - 507

JO - Molecular catalysis

JF - Molecular catalysis

M1 - 111549

ER -

Kalhor S, Zarei M, Sepehrmansourie H, Zolfigol MA, Shi H, Wang J et al. Novel uric acid-based nano organocatalyst with phosphorous acid tags: Application for synthesis of new biologically-interest pyridines with indole moieties via a cooperative vinylogous anomeric based oxidation. Molecular catalysis. 2021 May;507:111549. Epub 2021 Apr 20. doi: 10.1016/j.mcat.2021.111549