Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3

Anthony C. Coleman; Nicola M. Boyle; Conor Long; Ramunas Augulis; Audrius Pugzlys; Paul H.M. van Loosdrecht; Wesley R. Browne; Ben L. Feringa; Kate L. Ronayne; Mary T. Pryce

doi:10.1039/b925349c

Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3

Anthony C. Coleman, Nicola M. Boyle, Conor Long, Ramunas Augulis, Audrius Pugzlys, Paul H.M. van Loosdrecht, Wesley R. Browne, Ben L. Feringa, Kate L. Ronayne, Mary T. Pryce^*

^*Corresponding author for this work

Zernike Institute for Advanced Materials

Research output: Contribution to journal › Article › Academic › peer-review

4 Citations (Scopus)

Abstract

The femto- and picosecond time resolved spectroscopy of (η6-cis-stilbene)Cr(CO)3 provides evidence for three optically accessible excited states one leading to cis-trans isomerisation of the coordinated stilbene ligand and another which results in a slow release of CO.

Original language	English
Pages (from-to)	2201-2203
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	9
DOIs	https://doi.org/10.1039/b925349c
Publication status	Published - 2010

Keywords

EXCITED-STATE DYNAMICS
METAL-CARBONYLS
RESONANCE RAMAN
GAS-PHASE
ULTRAFAST PHOTODISSOCIATION
ELECTRONIC SPECTROSCOPY
MOLECULAR-STRUCTURE
PHOTOCHEMISTRY
FE(CO)(5)
CR(CO)(6)

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@article{d26cbb0944314284ac3f4e203867edff,

title = "Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3",

abstract = "The femto- and picosecond time resolved spectroscopy of (η6-cis-stilbene)Cr(CO)3 provides evidence for three optically accessible excited states one leading to cis-trans isomerisation of the coordinated stilbene ligand and another which results in a slow release of CO.",

keywords = "EXCITED-STATE DYNAMICS, METAL-CARBONYLS, RESONANCE RAMAN, GAS-PHASE, ULTRAFAST PHOTODISSOCIATION, ELECTRONIC SPECTROSCOPY, MOLECULAR-STRUCTURE, PHOTOCHEMISTRY, FE(CO)(5), CR(CO)(6)",

author = "Coleman, {Anthony C.} and Boyle, {Nicola M.} and Conor Long and Ramunas Augulis and Audrius Pugzlys and Loosdrecht, {Paul H.M. van} and Browne, {Wesley R.} and Feringa, {Ben L.} and Ronayne, {Kate L.} and Pryce, {Mary T.}",

note = "Relation: http://www.rug.nl/zernike/ Rights: University of Groningen, Zernike Institute for Advanced Materials",

year = "2010",

doi = "10.1039/b925349c",

language = "English",

volume = "39",

pages = "2201--2203",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "9",

}

TY - JOUR

T1 - Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3

AU - Coleman, Anthony C.

AU - Boyle, Nicola M.

AU - Long, Conor

AU - Augulis, Ramunas

AU - Pugzlys, Audrius

AU - Loosdrecht, Paul H.M. van

AU - Browne, Wesley R.

AU - Feringa, Ben L.

AU - Ronayne, Kate L.

AU - Pryce, Mary T.

N1 - Relation: http://www.rug.nl/zernike/ Rights: University of Groningen, Zernike Institute for Advanced Materials

PY - 2010

Y1 - 2010

N2 - The femto- and picosecond time resolved spectroscopy of (η6-cis-stilbene)Cr(CO)3 provides evidence for three optically accessible excited states one leading to cis-trans isomerisation of the coordinated stilbene ligand and another which results in a slow release of CO.

AB - The femto- and picosecond time resolved spectroscopy of (η6-cis-stilbene)Cr(CO)3 provides evidence for three optically accessible excited states one leading to cis-trans isomerisation of the coordinated stilbene ligand and another which results in a slow release of CO.

KW - EXCITED-STATE DYNAMICS

KW - METAL-CARBONYLS

KW - RESONANCE RAMAN

KW - GAS-PHASE

KW - ULTRAFAST PHOTODISSOCIATION

KW - ELECTRONIC SPECTROSCOPY

KW - MOLECULAR-STRUCTURE

KW - PHOTOCHEMISTRY

KW - FE(CO)(5)

KW - CR(CO)(6)

U2 - 10.1039/b925349c

DO - 10.1039/b925349c

M3 - Article

SN - 1477-9226

VL - 39

SP - 2201

EP - 2203

JO - Dalton Transactions

JF - Dalton Transactions

IS - 9

ER -