Preparation and mechanical properties of photo-crosslinked poly(trimethylene carbonate) and nano-hydroxyapatite composites

Mike A. Geven, Davide Barbieri, Huipin Yuan, Joost D. de Bruijn, Dirk W. Grijpma*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

11 Citations (Scopus)

Abstract

Composite materials of photo-crosslinked poly(trimethylene carbonate) and nanoscale hydroxyapatite were prepared and their mechanical characteristics for application as orbital floor implants were assessed. The composites were prepared by solvent casting poly(trimethylene carbonate) macromers with varying amounts of nano-hydroxyapatite and subsequent photocrosslinking. The incorporation of the nano-hydroxyapatite into the composites was examined by thermogravimetric analysis, scanning electron microscopy and gel content measurements. The mechanical properties were investigated by tensile testing and trouser tearing experiments. Our results show that nano-hydroxyapatite particles can readily be incorporated into photocrosslinked poly(trimethylene carbonate) networks. Compared to the networks without nano-hydroxyapatite, incorporation of 36.3 wt.% of the apatite resulted in an increase of the E modulus, yield strength and tensile strength from 2.2 MPa to 51 MPa, 0.5 to 1.4 N/mm(2) and from 1.3 to 3.9 N/mm(2), respectively. We found that composites containing 12.4 wt.% nano-hydroxyapatite had the highest values of strain at break, toughness and average tear propagation strength (376%, 777 N/mm(2) and 3.1 N/mm(2), respectively).

Original languageEnglish
Pages (from-to)3-11
Number of pages9
JournalClinical hemorheology and microcirculation
Volume60
Issue number1
DOIs
Publication statusPublished - 2015

Keywords

  • Composites
  • photo-crosslinked poly(trimethylene carbonate)
  • nano-hydroxyapatite
  • orbital floor repair
  • IN-VITRO DEGRADATION
  • ORBITAL FLOOR
  • BONE
  • BIOMATERIALS
  • SCAFFOLDS
  • PHOSPHATE
  • REPAIR
  • RECONSTRUCTION
  • REGENERATION

Cite this