Pyrazine Revisited

Karel E. Drabe; Harry Th. Jonkman; Jan Kommandeur

Pyrazine Revisited

Karel E. Drabe
, Harry Th. Jonkman
, Jan Kommandeur

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Abstract

Pyrazine is shown by its Molecular Eigenstate Spectra and by its quantum beats to be a small molecule. The effect of Coriolis coupling and non-resonant light scattering are discussed. This paper further treats the so-called "fast component". Its existence with a decay time of about 100 psec has by now been firmly established. It finds its cause in the "bunching" of the molecular eigenstates in frequency space. For broad (i.e. psec) lasers it is therefore still useful to speak of pyrazine as an ILS-molecule. The characterization depends on the laser one uses in the experiment.

Original language	English
Number of pages	8
Journal	The Journal of Chemical Physics
Volume	84
Issue number	1
Publication status	Published - 1986

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@article{d6781f42b128479b8bf8c925172a708b,

title = "Pyrazine Revisited",

abstract = "Pyrazine is shown by its Molecular Eigenstate Spectra and by its quantum beats to be a small molecule. The effect of Coriolis coupling and non-resonant light scattering are discussed. This paper further treats the so-called {"}fast component{"}. Its existence with a decay time of about 100 psec has by now been firmly established. It finds its cause in the {"}bunching{"} of the molecular eigenstates in frequency space. For broad (i.e. psec) lasers it is therefore still useful to speak of pyrazine as an ILS-molecule. The characterization depends on the laser one uses in the experiment.",

author = "Drabe, \{Karel E.\} and Jonkman, \{Harry Th.\} and Jan Kommandeur",

note = "Relation: http://www.rug.nl/scheikunde/ date\_submitted:2006 Rights: University of Groningen. Materials Science Centre",

year = "1986",

language = "English",

volume = "84",

journal = "The Journal of Chemical Physics",

publisher = "AMER INST PHYSICS",

number = "1",

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TY - JOUR

T1 - Pyrazine Revisited

AU - Drabe, Karel E.

AU - Jonkman, Harry Th.

AU - Kommandeur, Jan

N1 - Relation: http://www.rug.nl/scheikunde/ date_submitted:2006 Rights: University of Groningen. Materials Science Centre

PY - 1986

Y1 - 1986

N2 - Pyrazine is shown by its Molecular Eigenstate Spectra and by its quantum beats to be a small molecule. The effect of Coriolis coupling and non-resonant light scattering are discussed. This paper further treats the so-called "fast component". Its existence with a decay time of about 100 psec has by now been firmly established. It finds its cause in the "bunching" of the molecular eigenstates in frequency space. For broad (i.e. psec) lasers it is therefore still useful to speak of pyrazine as an ILS-molecule. The characterization depends on the laser one uses in the experiment.

AB - Pyrazine is shown by its Molecular Eigenstate Spectra and by its quantum beats to be a small molecule. The effect of Coriolis coupling and non-resonant light scattering are discussed. This paper further treats the so-called "fast component". Its existence with a decay time of about 100 psec has by now been firmly established. It finds its cause in the "bunching" of the molecular eigenstates in frequency space. For broad (i.e. psec) lasers it is therefore still useful to speak of pyrazine as an ILS-molecule. The characterization depends on the laser one uses in the experiment.

M3 - Article

VL - 84

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

IS - 1

ER -

Pyrazine Revisited

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