Pyridinediols as HCI Receptors; Formation of an Unusual PyridineOHCI Complex in Conjunction with the Preparation of Lewis Acidic Titanium(iv) Centres

JJH Edema*, AM Ridder, RM Kellogg, F van Bolhuis, H Kooijman, AL Spek, Rob Libbers

*Corresponding author for this work

    Research output: Contribution to journalArticleAcademicpeer-review

    Abstract

    Reaction of pyridinediols 1 with TiCl4 affords in one case an unusual dehydration-HCl complexation; in conjunction with these results, reaction of 1 with HCI indicates a strong affinity of these diols for (Lewis) acids.

    Original languageEnglish
    Pages (from-to)625-627
    Number of pages3
    JournalJournal of the Chemical Society-Chemical Communications
    Issue number7
    Publication statusPublished - 7-Apr-1993

    Keywords

    • DIELS-ALDER REACTION
    • LIGANDS
    • REAGENT

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